Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Reactions of Trimethylsilyldiphenylphosphine with Isocyanates

트리메틸실릴디페닐포스핀과 이소시아네이트와의 반응

  • Song Yoon Han (Department of Chemistry, College of Liberal Arts and Sciences, Dong Guk University) ;
  • Tae Jin Min (Department of Chemistry, College of Liberal Arts and Sciences, Dong Guk University) ;
  • Dong Yul Lee (Department of Chemistry, College of Liberal Arts and Sciences, Dong Guk University) ;
  • Il Kyu Lee (Department of Chemistry, College of Liberal Arts and Sciences, Dong Guk University)
  • 한송윤 (동국대학교 문리과대학 화학과) ;
  • 민태진 (동국대학교 문리과대학 화학과) ;
  • 이동율 (동국대학교 문리과대학 화학과) ;
  • 이일규 (동국대학교 문리과대학 화학과)
  • Published : 1971.12.30
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Abstract

Reactions of trimethylsilyldiphenylphosphine with phenylisocyanate and ethylisocyanate were studied at various temperatures for 3 days. Trimethylsilyldiphenylphosphine gave cyclic dimer, cyclic trimer and diphenylcarbodiimide from phenylisocyanate, but gave cyclic trimer, triethylisocyanurate, only from ethylisocyanate. In these reactions, it is suggested that trimethylsilyldiphenylphosphine was used to be an effective catalyst for cyclization of isocyanates.

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References

  1. Advances in Organometallic Chemistry v.5 M. F. Lappert;B. Prokai
  2. Organic Insertion Reactions of Group IV Elements E. Y. Lukevits;M. G. Voronkov
  3. Angew. Chem. v.77 H. Schmidbauer
  4. Advances in Inorganic and Radio-chemistry v.6 U. Wannagat
  5. Trans. Faraday Soc. v.60 E. W. Abel;R. P. Bush;C. R. Jenkins;T. Zobei
  6. Chem. Commun. K. Itoh;S. Sakai;Y. Ishii
  7. Nippon Gogyo-kagakukaisi v.70 K. Itoh;S. Sakai;Y. Ishii
  8. Trans. Faraday Soc. v.62 E. W. Abel;D. A. Armitage;D. B. Brady
  9. Chem. Ber. v.97 G. Oertel;H. Malz;H. HoltSchmidt
  10. Chem. Ber. v.97 W. Fink
  11. At the 18th, meeting of Chem. Soc. of Japan no.23213 A. G. Davies;Y. Ishii
  12. J. Chem. Soc. A. J. Bloodworth;A. G. Davies
  13. At the meeting of Chem. Soc. of Japan no.17124 K. Itoh;S. Sakai;Y. Ishii
  14. J. Chem. Soc., (C) K. Itoh;Il Kyu Lee;S. Sakai;Y. Ishii
  15. J. Chem. Soc., (C) K. Itoh;Il Kyu Lee;S. Sakai;Y. Ishii
  16. J. Chem. Soc. (A) E. W. Abel;L. H. Saubberwal
  17. Chem. Ber. v.97 J. Pump;E. G. Rochow
  18. Chem. Ber. v.92 W. Kuchen;H. BuchWald
  19. J. Chem. Soc. Chatt;Hart
  20. J. Amer. Chem. Soc. v.88 H. E. Buckles;L. A. Mcgrew
  21. The infrared spectra of complex molecules L. J. Bellamy