Abstract
Endothermic peak of transformation of ${\gamma}-MnO_2$ was obviously shown by differential heating curve in the present study, and the transformation temperature was different from other modification. ${\gamma}-MnO_2$ carried out to analyze exclusively, by means of the half area method in corresponding endothermic peak of differential heating curve. ${\alpha}-\;and\;{$beta}-MnO_2$ (Pyrolusite) containing in sample about 75% is interfered about ${\pm}$10% of the relative error, and while those of below 50% is interfered about ${\pm}$5%.
${\gamma}-MnO_2$는 示差熱曲線에서 結晶變移의 吸熱 peak가 明白하게 나타났으며 他變態의 轉移溫度 와 相異하였다. 本 peak를 利用하여 半面積法으로 ${\gamma}-MnO_2$만의 定量分析을 檢討하였다. 相對誤差 ${\pm}$5%範圍內에서 試料 50mg∼300mg까지 定量할 수 있었다. ${\alpha},{$beta}-MnO_2$ (pyrolusite)가 妨害物質로서 約 75%까지 混合될경우에도 相對誤差는 ${\pm}$10%程度였으며 約 50%以內가 混合될 경우에는 相對誤差 ${\pm}$5%以內로서 거의 영향이 없었다.