대한화학회지 (Journal of the Korean Chemical Society)

  • 제15권5호
  • /
  • Pages.219-222
  • /
  • 1971
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

브롬화벤젠의 알코올에 의한 용매분해에 관한 반응속도론적 연구

Kinetics of the Solvolysis of Benzyl Bromides in Alcohols

  • Yong-Jin Lim (Department of Chemistry, Kyungpook National University) ;
  • Soo-Dong Yoh (Department of Chemistry, Kyungpook National University) ;
  • Soon-Yung Hong (Department of Chemistry, Kyungpook National University)
  • 발행 : 1971.10.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The kinetics of the solvolysis of benzyl and p-or m-substituted benzyl bromides in various alcohols have been determined by an electric conductivity method. From these reactions, a curved Hammett plot is obtained and a mechanism is proposed to account for the nonlinear behavior observed. In addition, effects of solvent polarity on the activation parameters for the solvolysis of benzyl bromides are discussed.

키워드

참고문헌

  1. J. Chem. Soc. J. W. Baker
  2. J. Am. Chem. Soc. v.70 C. G. Swain;R. W. Eddy
  3. J. Am. Chem. Soc. v.73 S. Winstein;E. Grunwald;H. Walter Jones
  4. J. Am. Chem. Soc. v.77 C. G. Swain;R. B. MoseIy;D. E. Bown
  5. J. Am. Chem. Soc. v.77 C. G. Swain;D. C. Dittmer;L. E. Kaiser
  6. J. Am. Chem. Soc. v.84 J. W. Hill;A. Fry
  7. J. Am. Chem. Soc. v.84 J. B. Hyne;R. Wills;R. E. Wonkka
  8. J. Am. Chem. Soc. v.84 B. L. Murr, Jr.;V. J. Shiner, Jr.
  9. Nature v.171 C. W. L. Bevan;E. D. Hughes;C. K. Ingold
  10. This Journal v.9 I. Lee
  11. University Journal, Pusan National University v.10 E. S. Lee;S. K. Lee
  12. Physical Organic Chemistry L. P. Hammett
  13. J. Am. Chem. Soc. v.73 C. G. Swain;W. P. Langsdorf, Jr.
  14. J. Am. Chem. Soc. v.81 R. Fuchs;A. Nisbet.
  15. J. Am. Chem. Soc. v.85 R. Fuchs;D. M. Carlton
  16. Bull. Soc. Chim. France v.4 R. Quelet;J. Allard
  17. This Journal v.13 S. D. Yoh;D. S. Lee;S. Y. Hong
  18. Phil. Mag. v.I E. A. Guggenheim
  19. Can. J. Chem. v.33 R. E. Robertson
  20. Progress in Phys. Org. Chem. v.2 C. D. Ritchie;W. F. Sager
  21. Solvolysis Mechanism E. R. Thornton
  22. J. Chem. Educ. v.48 J. O. Schreck
  23. J. Am. Chem. Soc. v.72 J. W. Hackett;H. C Thomas
  24. Mechanism and Structure in Organic Chemistry E. S. Gould
  25. Kinetics and Mechanism A. A. Frost;R. G. Pearson