Kinetics of the Solvolysis of Benzyl Bromides in Alcohols

브롬화벤젠의 알코올에 의한 용매분해에 관한 반응속도론적 연구

  • Yong-Jin Lim (Department of Chemistry, Kyungpook National University) ;
  • Soo-Dong Yoh (Department of Chemistry, Kyungpook National University) ;
  • Soon-Yung Hong (Department of Chemistry, Kyungpook National University)
  • Published : 1971.10.30

Abstract

The kinetics of the solvolysis of benzyl and p-or m-substituted benzyl bromides in various alcohols have been determined by an electric conductivity method. From these reactions, a curved Hammett plot is obtained and a mechanism is proposed to account for the nonlinear behavior observed. In addition, effects of solvent polarity on the activation parameters for the solvolysis of benzyl bromides are discussed.

Keywords

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