Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Solvolysis of p-Chlorobenzyl Chloride in Various Aqueous Mixtures

여러가지 물혼합용매 속에서 p-Chlorobenzyl Chloride의 가용매분해

  • Lee, Suk-Kee (Department of Chemistry, College of Liberal Arts and Sciences, Pusan National University) ;
  • Lee, Euk-Suk (Department of Chemistry, College of Liberal Arts and Sciences, Pusan National University)
  • 이석기 (부산대학교 문리과대학 화학과) ;
  • 이억석 (부산대학교 문리과대학 화학과)
  • Published : 1971.08.30
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Abstract

The thermodynamic parameters for the solvolysis of the p-chlorobenzyl chloride taking place in the various aqueous mixtures were determined. From the application of these data to the formula ${\delta}_M{\Delta}H^{\neq}=a'Y+b{\delta}_M{\Delta}S^{\neq}$ the following conclusion was obtained: That the substrate constant a' differs in different aqueous solvent was found, and using each a' value the solvolysis mechanism of p-chlorobenzyl chloride in each aqueous mixture can be determined.

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References

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