대한화학회지 (Journal of the Korean Chemical Society)

  • 제15권1호
  • /
  • Pages.15-22
  • /
  • 1971
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

DL-1-Aminoalkyl Phosphonic Acids와 그유도체들의 합성 (I)

Synthesis of DL-1-Amino Alkyl Phosphonic Acids and their Derivatives

  • Cho Kyung Yeon (Department of Chemical Engineering, College of Science and Engineering Korea University) ;
  • Kim Duck Chan (Department of Chemical Engineering, College of Science and Engineering Korea University) ;
  • Kim Yong Joon (Department of Chemical Engineering, College of Science and Engineering Korea University)
  • 발행 : 1971.02.28
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초록

DL-1-Amino-pentyl phosphonic acid, DL-1-Aminopropyl phosphonic acid were synthesized with good yield from caproic acid and butyric acid using the modified Curtius reaction and N-derivatives, N-acetyl-DL-1-amino propyl phosphonic acid, N-acetyl-DL-1-aminopentyl phosphonic acid, N-Benzoyl-DL-1-amino-propyl phosphonic acid, were also prepared by a variety of methods including the Schotten-Baumann reaction. In addition, the chemical and physical properties of the products were investigated. All the products were also identified by means of elemental analysis, Infrared spectrophotometry, Ninhydrin test, and the determination of the neuralization equivalent.

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