Nuclear Engineering and Technology

  • 제3권4호
  • /
  • Pages.198-202
  • /
  • 1971
  • /
  • 1738-5733(pISSN)
  • /
  • 2234-358X(eISSN)
한국원자력학회 (Korean Nuclear Society)
권호 표지

Kinetic Studies on the Halide Exchange Reactions of Some Substituted Benzyl Chlorides

  • Lee, Ikchoon (Dept. of Applied Chem, College of Engineering, Seoul National University) ;
  • Lee, Bon-Su (Dept. of Applied Chem, College of Engineering, Seoul National University) ;
  • Yie, Jae-Eui (Dept. of Applied Chem, College of Engineering, Seoul National University)
  • 발행 : 1971.12.01
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초록

방사성동위원소로 표지된 할라이드 이온과 염화벤질간의 할로겐 교환반응을 아세톤 용액에서 반응속도론적으로 연구하였다. 결과로 전보에서 얻은 결론대로 교환반응속도가 기질과 할라이드 이온의 편극화율에 의하여 좌우됨을 알았다.

Kinetic studies on the halide exchange reactions of some substituted benzyl chlorides have been carried out using radioisotope tracer halide ions. Results are consistent with our previous conclusion that the rates of halide exchange reactions in acetone with arylmethy halides are dictated by the porarizabilities of both substrate and nucleophile.

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