Polarography에 依한 Cupric-thiocyanate의 Kinetics와 Cuprous-thiocyanate의 Adsorption Wave에 關한 硏究

Polarographic Studies on the Kinetics of Cu(II)-thiocyanate and the Adsorption Wave of Cu(I)-thiocyanate

  • 황정의 (慶北大學校 文理科大學 化學科) ;
  • 정종재 (慶北大學校 文理科大學 化學科) ;
  • 손무용 (慶北大學校 文理科大學 化學科) ;
  • 박유철 (慶北大學校 文理科大學 化學科)
  • 발행 : 19700900

초록

In the presence of hydrogen peroxide, the effects of temperature and pH to the catalytic reaction velocity of cupric -thiocyanate and the quantities of reduction products adsorbed on the D.M.E. have been studied by polarographic method. According to these experiments, the following empirical equation has been derived for the relation among temperature $T_i$, concentration of hydrogen ion $pH_i$ and adsorbed cuprous-thiocyanate in moles/$cm^2Z_{ij}$, and rate constant log$K_{ij}$ $$log\;K_{ij}=\frac{1}{T_i}\{A(pH_j)+B\}+C(pH_j)+D$$ $$Z_{ij}=\frac{1}{T_i}\{{\alpha}(pH_j)^{\frac{1}{2}}+{\beta}\}+{\gamma}(pH_j)^{\frac{1}{2}}+{\delta}$$ where, A,B,C,D and {$\alpha},{\beta},{\gamma},{\delta}$ are constants. The Calculated values by both equations are well agreed with empirical values within 8% in the error.

키워드

참고문헌

  1. 日本化學會誌 v.88 野崎亨(et al.)
  2. J.A.C.S. v.73 L.Meites
  3. Anal. Chem. v.22 R.G. Kitson
  4. Zhr. Anal. Kim. v.13 V.N. Podchinova;S.P. Onosova
  5. Polarography v.I;II I.M. Kolthoff;J.J. Lingane
  6. J.A.C.S. v.82 I.M. Kolthoff;Y. Okinaka
  7. J.A.C.S. v.74 P.Delahay;G.L. Stichl
  8. Collection Czechoslov chem. Comm. v.12 R. Brdicka;K. Wiesner
  9. Z.Electrochem. v.48 R.Brdicka
  10. J.A.C.S. v.74 P. Delahay
  11. J.A.C.S. v.73 D.N.Hume;D.D.Deford;G.C.S Cave
  12. Journal of the Korean Chemical Society v.13 黃正儀;鄭宗在;孫武龍
  13. J.A.C.S. v.73 I.M. Kolthoff;E.P. Parry
  14. Trans. Faraday. Soc. v.42 J.H. Baxendale(et al.)