Derivation of the WLF Equation from the Theory of Rate Process

WLF 점도식의 반응속도론에 의한 도출

  • Ree, Tai-Kyue (Korea Institute of Science and Technology, Department of Chemistry, University of Utah) ;
  • Jhon, Mu-Shik (Korea Institute of Science and Technology, Department of CHemistry, Dong Guk University)
  • 이태규 (한국과학기술연구소, 미국유타대학교 화학과) ;
  • 전무식 (한국과학기술연구소, 동국대학교 화학과)
  • Published : 19700300

Abstract

The WLF equation is derived from the theory of rate processes in conjunction with the theory of liquids of significant structures. The empirical parameters in the WLF equation are discussed and compared with the corresponding quantities in the derived equation.

"Significant liquid structure"의 이론과 반응 속도 이론을 이용 WLF점도식 꼴을 도출하였다. 반 실험적 WLF 점도식 내 실험 Parameter와 도출된 이론식 중의 해당된 항을 비교 검토하였다.

Keywords

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