대한화학회지 (Journal of the Korean Chemical Society)

  • 제13권4호
  • /
  • Pages.347-353
  • /
  • 1969
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

小員環 化合物에 關한 硏究 (II) 2-Butenedial Ditosylhydrazone 熱分解에 있어서의 Tetrahedrane 生成에 關하여

Studies on the Strained Ring Compound System (II) The Formation of Tetrahedrane in the Pyrolysis of 2-Butenedial Ditosylhydrazone

  • 이학기 (慶北大學校 文理科大學)
  • Hak-Ki Lee (College of Liberal Arts and Science Kyungpook National University)
  • 발행 : 19691200
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초록

trans-1, 4-Dideutero-2-butenedial ditosylhydrazone has been synthesized to investigate the path of the acetylene formation in the pyrolysis of the dry lithium salt. Mass spectra showed that three isotope isomers of acetylene which might come from the strained ring compound, tricyclo[1, 1, 0, ] butane, were formed.

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참고문헌

  1. 本誌 v.13 李學沂
  2. J. Am. Chem. Soc. v.55 H. Gilman;G. Wright
  3. Discussions Faraday Soc. v.19 Bak, Hansen
  4. Aca Chem. Scand v.6 N. Elming;Clauson-kaas
  5. J. Am. Chem. Soc. v.74 D. Hufford;D. Tarbell
  6. U.S. 2,515,304 D. Jones
  7. C. A. v.44 D. Jones
  8. J. Am. Chem. Soc. v.85 G. L. Closs;L. E. Closs
  9. J. Am. Chem. Soc. v.87 G. Kaufman;H. Shechter
  10. J. Am. Chem. Soc. v.87 J. Smith;H. Shechter
  11. J. Am. Chem. Soc. v.88 K. Wiberg;M. Lavanish
  12. Catalog of Mass Spectra Data