참고문헌
- This Journal v.13 J. S. Oh;W. S. Kwak
- J. Am. Chem. Soc. v.74 R. G. Charles;H. Freiser
- Ber. v.34 Knoevenagel
- J. Am. Chem. Soc. v.79 A. M. Osman
- Ber. v.30 Kehrman
대한화학회지 (Journal of the Korean Chemical Society)
- 제13권4호
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- Pages.309-312
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- 1969
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- 1017-2548(pISSN)
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- 2234-8530(eISSN)
2,5-Diamine 1,4-Dihydroxybenzene과 금속 (II) 이온이 만드는 Coordination Polymer에 관하여
Study on the Coordination Polymers of Metal (II) Ions with 2,5-Diamine 1,4-Dihydroxybenzene
- Joon Suk Oh (Department of Chemistry, Sogang Jesuit College) ;
- Kyun Ok Cho (The Research Institute of Mining and Metallurgy)
- 발행 : 19691200
초록
A series of metal ion-2, 5-diamine 1, 4-dihydroxybenzene polymers containing copper(II), nickel(II) or cobalt (II) have been prepared. The structure was postulated on the basis of elementary analysis of polymers. It was found that copper polymer is most likely the coordination polymers by X-ray powder pattern studies. The thermal stability of the polymers was also studied by a simple method, utilizing a thermogravimetric balance. The order of thermal stabilities is Cu(II) > Ni(II) > Co(II). The polymers start to decompose at a relatively low temperature.
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