대한화학회지 (Journal of the Korean Chemical Society)

  • 제11권3호
  • /
  • Pages.105-110
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  • 1967
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  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

액체 구조의 천이상태이론의 질소산화물들에 대한 적용

Transient State Theory of Significant Liquid Structure Applied to Nitrogen Oxides

  • 김상형 (서울대학교 문리과대학 화학과) ;
  • 박형석 (서울대학교 문리과대학 화학과) ;
  • 김각중 (서울대학교 문리과대학 화학과) ;
  • 장세헌 (서울대학교 문리과대학 화학과)
  • Kim, Sang-Hyung (Department of Chemistry, College of Liberal Arts and Sciences, Seoul National University) ;
  • Pak, Hyung-Suk (Department of Chemistry, College of Liberal Arts and Sciences, Seoul National University) ;
  • Kim, Kak-Choong (Department of Chemistry, College of Liberal Arts and Sciences, Seoul National University) ;
  • Chang, Sei-Hun (Department of Chemistry, College of Liberal Arts and Sciences, Seoul National University)
  • 발행 : 19670900
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초록

액체구조의 천이상태이론을 아산화질소($N_2O$)와 사산화질소($N_2O_4$)에 적용하여 이 액체들의 상태합을 유도하였다. 이상태합들을 써서 각 액체의 몰부피, 증기압, 증발엔트로피, 임계점에서의 성질 등, 여러가지 열역학적양들을 계산한 결과 모두 실험치와 좋은 일치를 얻었다.

The transient state theory of significant liquid structure is applied to nitrous oxide and nitrogen tetroxide. The partition functions for the two liquids are derived according to the transient state theory. The various thermodynamic properties; such as, molar volumes, vapor pressures, entropies of vaporization, and critical point properties agree well with the experimental values.

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참고문헌

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