Thermodynamic Parameters for Micelle Formation of Dodecylpyridinium Chloride

Dodecylpyridinium Chloride의 micelle 形成의 熱力學變數

  • Han, Man-Un (Department of Chemistry, College of Sciences and Engineering, Korea University)
  • 한만운 (高麗大學校 理工大學 化學科)
  • Published : 19660600

Abstract

The effect of temperature on the critical micelle concentration of dodecylpyridinium chloride has been determined by electrical conductance method over the range from $5^{\circ}C\;to\;50^{\circ}C$. The values of the change in heat content, ${\Delta}H_m$, and the other thermodynamic parameters have been estimated using the equation of temperature dependence on the critical micelle concentration for the same temperature range. The significance of these thermodynamic quantities and their relations to the various current theories of micelle forming processes were discussed.

Keywords

References

  1. Trans. Faraday Soc. v.46 G. Stainsby;A. E. Alexander
  2. J. Colloid Sci. v.8 B. D. Flockhart;A. R. Ubbelohde
  3. J. Colloid Sci. v.16 B. D. Flockhart
  4. J. Phys. Chem. v.61 E. D. Goddard;C. A. Hoeve;G. C. Benson
  5. J. Colloid Sci. v.13 P. White;G. C. Benson
  6. J. Phys. Chem. v.60 E. J. Hutchinson;L. Winslow
  7. J. Am. Chem. Soc. v.73 D. N. Eggenberger;H. J. Harwood
  8. J. Colloid Sci. v.19 J. E. Adderson;H. Taylor
  9. Synthetic Organic Chemistry R. B. Wagner;H. D. Zook
  10. Fatty acids and their Derivatives A. W. Ralstone
  11. J. Am. Chem. Soc. v.49 J. B. Conant;N. F. Hall
  12. J. Am. Chem. Soc. v.52 G. B. Conant;T. H. Werner
  13. Anal. Chem. v.24 C. W. Pifer;E. G. Wallish
  14. J. Am. Chem. Soc. v.61 M. E. L. McBain;W. B. Dye;S. A. Johnston
  15. J. Phys. Chem. v.66 K. W. Herrmann
  16. Trans. Faraday Soc. v.54 E. Matijevic;B. A. Pethica
  17. J. Phys. Chem. v.66 K. Shinoda;E. J. Hutchinson
  18. J. Phys. Chem. v.62 P. Mukerjee;K. J. Mysels;C. I. Dulin
  19. J. Chem. Phys. v.13 H. S. Frank;W. W. Evans
  20. Discussion Fraraday Soc. v.24 H. S. Frank;W. Y. Wen