Phenol과 DMA 간의 수소결합

Intermolecular Hydrogen Bond between Phenol and DMAs

  • 김복혜 (원자력연구소 화학연구실) ;
  • 이익춘 (서울 공대 응용화학과)
  • Kim, Pock-Hye (Chemistry Division, Atomic Energy Research Institute) ;
  • Lee, Ik-Choon (Department of Applied Chemistry, College of Engineering, Seoul National University)
  • 발행 : 19660300

초록

Phenol과 각 종 Dimethylaniline(DMA)간의 수소결합을 Infrared Spectrophotometer로 연구하였다. 일반으로 DMA는 n-donor 및 ${\pi}$-donor의 2중 역활을 하나 주로 n-donor로 작용하며 phenol의 O-H stretching frequency의 shift(${\Delta}{\nu}$)는 DMA의 basicity에 비례하였고 (${\Delta}{\nu}$) 와 Hammett의 σcontant사이에는 linearity가 성립함을 알았다.

Intermolecular hydrogen-bonding between phenol and N,N'-dimethylanilines (DMA) has been studied by infrared spectrophotometry. Results show that DMA acts as n-and ${\pi}$-donor although n-complex predominates. O-H stretching frequency shifts (${\Delta}{\nu}$) were proportional to basicitys of DMA and excellent linearity was observed between ${\Delta}{\nu}$ and the Hammett substituent constant, ${\sigma}$.

키워드

참고문헌

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