Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Significant Structure of Liquid Methyl Halides

할로겐화 메틸의 액체구조와 성질

  • Lee, Hai-Bang (Department of chemistry, Dong Guk University) ;
  • Chang, Sei-Hun (Department of Chemistry, College of Liberal Arts and Sciences, Seoul National University)
  • Published : 19651200
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Abstract

The partition function of liquid methyl chloride and methyl bromide are developed by applying the significant structure theory of liquid.$^{(1-3)}$ The parameters therein are determined by the modified significant structure theory of liquid.$^{(4)}$ The molar volume, the vapor pressure, and the entropy of vaporization of the liquids are calculated over a wide temperature range. The critical properties for the liquids are also calculated. The results show good agreement with experimental observations.

H.Eyring과 그의 공동 연구자들이 발전시킨 액체이론$^{(1-3)}$에 따라서 할로겐화 메틸의 분배함수를 구하였으며 이에 포함된 parameters은 장세헌과 그의 공동 연구자들이 개정한 방법$^{(4)}$에 따라서 구하였다. 이 분배함수로부터 여러가지 열역학적 양들을 계산하여 실험치와 비교하여 본 결과 매우 잘 맞었다.

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References

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