Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Halogen Exchange Reactions of Benzyl Halides (Part I) Kinetics of Reactions of Chloride and Bromide Ions with Benzyl Chloride and Bromide

벤질할라이드의 할로겐交煥反應 (第 1 報) 鹽化 및 臭化 벤질과 鹽素 및 臭素이온과의 反應速度

  • Published : 19650900
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Abstract

Kinetics of reactions of chloride and bromide ions with benzyl chloride and bromide have been investigated in 90% ethanol solution. Semi-quantitative analysis of the results shows that the bond-formation is more important than the bond-breaking and furthermore in bond-formation the energy gain due to bond-formation is less than the increase in electron affinity of the nucleophile.

Benzyl chloride 및 bromide와 chloride 및 bromide ion 간의 반응을 90% ethanol 용액에서반응속도론적으로 연구하였다. 반 정량적인 결과의 해석은 bond-formation 이 bond-breaking보다 더 중요하고 또 결합형성 과정에서는 형성으로 얻은 energy보다는 nucleophile의 electron affinity의 증가로 인한 차이가 더 중요함을 보여주고 있다.

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