Hot Atom Chemistry of Aromatic Halides : Scavenger, Temperature and Oxygen Effect

芳香族할라이드의 Hot Atom Chemistry 스캐벤져, 溫度 및 酸素의 效果

  • 최재호 (原子力硏究所 化學硏究室) ;
  • 박용찬 (原子力硏究所 化學硏究室) ;
  • 손미자 (原子力硏究所 化學硏究室)
  • Published : 19650600

Abstract

The organic yields(i.e., fraction of nuclear events resulting in organic compound formation) of the radioactive neutron capture reactions of the halogens in purified aromatic halides have been determined in the liquid and solid state, in the presence of scavenger, elemental halogen for thermal atoms, and in the presence of oxygen. Among the important results are; (1) organic yields of the halides are due in part to hot processes and in part to thermal processes; (2) temperature (from liquid state to solid state); (3) the organic yield of chlorobenzene is the same in the solid phase as in the liquid phase whereas the yields of the bromo-and iodobenzene are higher in the solid.

Keywords

References

  1. J. Am. Chem. Soc. v.69 W.F. Libby
  2. Nucleonics v.2 no.6 R.R. Edwards;T.H. Davis
  3. J. Am. Chem. Soc. v.74 S. Goldhaber;J.E. Willard
  4. J. Am. Chem. Soc. v.74 G.Levey;J.E. Willard
  5. J. Am. Chem. Soc. v.75 J.F. Horning;J.E. Willard
  6. J. Am. Chem. Soc. v.82 Peder J. Estrup;Richard Wolfgang
  7. J. Am. Chem. Soc. v.77 J.C.W. Chien;E. Willard
  8. J. Am. Chem. Soc. v.79 J.C.W. Chien;J.E. Willard
  9. J. Am. Chem. Soc. v.79 Adon A. Gordus;J.E. Willard
  10. J. Am. Chem. Soc. v.73 S.Goldhaber;R.S.H. Chiang;J.E. Willard
  11. J. Am. Chem. Soc. v.75 J.C.W. Chien;J.E. Willard
  12. J. Chem. Phys. v.20 M.S. Fox;W.F. Libby
  13. J. Chem. Phys. v.17 Lewis Friedman;W.F. Libby