대한화학회지 (Journal of the Korean Chemical Society)

  • 제9권1호
  • /
  • Pages.45-48
  • /
  • 1965
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

分光光度法에 依한 Cu(II)-Oxamidoxime의 錯物에 關한 硏究

Studies on Copper (II)-Oxamidoxime Complex by Spectrophotometric Method

  • 오상오 (慶北大學校 文理科大學) ;
  • 도재철 (慶北大學校 文理科大學)
  • Oh, Sang O. (College of Liberal Arts and Sciences, Kyungpook National University) ;
  • Do, Che-Chul (College of Liberal Arts and Sciences, Kyungpook National University)
  • 발행 : 19650300
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초록

Stability constant, composition of copper (II)-oxamidoxime complex were determined by spectrophotometric method. The ratio of copper (II) and oxamidoxime in the above complex was 1 : 1, and its stability constant was calculated to be $2.4{\times}10^{22}$. The complex solution gave constant absorbancy between the pH range of 4.5 to 6 at 600 $m{\mu}$ in which Beer's law applicable in the concentration range of 0.3 to 2.0 ppm studied in this work. It was noted that some metals such as Fe(III), Ni(II), Co(II), U(VI) interfere copper determination by this method.

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