Abstract
The partition function of liquid ammonia was developed by applying the modified significant structure theory of liquid.$^5$ The molar volume, vapor pressure, vaporization entropy were calculated over a wide temperature range. The critical properties for the liquid were also calculated. And surface tensions of the liquid were calculated in a similar manner developed for water by Chang and Pak.$^{10}$ The results show good agreement with experimental observations.
Modified significant structure theory of liquid를 써서 액체 암모니아의 partition function을 정하여 액체 암모니아의 몰부피, 증기압, 한계점, 증발엔트로피, 표면장력을 계산한 결과 실측치와 잘 맞는 값을 얻었다.