Spectrophotometric Determination of Ti(IV) by means of Methylthymolblue(MTB) Complex

Methylthymolblue(MTB)에 依한 Ti(IV)의 吸光光度分析

  • Doo Won Park (Graduate School, Kyung Pook National University) ;
  • Chong Nam Lee (Depastment of Chemistry, Kung Pook National University)
  • Published : 19631200

Abstract

A method of the colorimetric determination of titanium has been developed, based on the fact (IV) forms a stable blue complex with methylthymolblue(MTB) which is suitable for spectrophotometric determination of titanium in the concentration range of 0.2 to 22 $\mu$g per ml as $TiO_2$. The determination was carried out in the solution of pH range of 2.6 to 3.6, and the absorbancy of complex was at 600m$\mu$ with Coleman spectrophotometer. Titanium forms a 1:1 complex with MTB, which has a molar absorptivity, $1.1{\times}10^4$ at 600m\mu$. The effects of hydrogen ion concentration, reagent concentration, stability of complex, and hydrolysis were studied. Most of cations do not interfere seriously; however, many of anions such as oxalate, citrate, phosphate, chloride interfere in this determination.

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