초록
Cobalt(Ⅲ) ion gives two step waves with $E_{1/2}$-0.1V(?)(vs.S.C.E.) and $E_{1/2}$-1.37V(vs. S.C.E.) from a base electrolyte consisting of 0.1 M TEA+sodium borate+0.0002% gelatin. The first wave results from the reduction Co(Ⅲ) to Co(Ⅱ). The second wave corresponding to the reduction Co(Ⅱ) to Co(0) and this wave is diffusion controlled. The diffusion current constant of the second wave is 2.7. Under these-conditions, diffusion current of the second wave is proportional to the concentration of Co (Ⅱ) in the range of $10^{-3}{\sim}10^{-4}$ M.