Photoluminescence Properties of $Eu^{3+}-Activated\;YCa_3(GaO)_3(BO_3)_4$ phosphor

  • Lee, Dae-Won (Advanced Materials Division, Korea Research Institute of Chemical Technology) ;
  • Kwak, Chung-Heop (Advanced Materials Division, Korea Research Institute of Chemical Technology) ;
  • Jung, Ha-Kyun (Advanced Materials Division, Korea Research Institute of Chemical Technology)
  • Published : 2006.08.22

Abstract

A borate compound was adopted as new host material for $EU^{3+}$ activator. The $Eu^{3+}-doped\;YCa_3(GaO)_3(BO_3)_4$ (YCGB) phosphors were successfully synthesized. Also, their photoluminescence properties under the excitation of UV ray were measured. In the XRD patterns of the synthesized powders, most peaks were well-matched to a gaudefroyite phase. The emission of $Eu^{3+}$ in YCGB consists of a strong peak centered at 622 nm, which is attributed to $^5D_O-^7F_2$ transition of $Eu^{3+}$ and several weak peaks at near the wavelength. Optimum $Eu^{3+}$ concentration of the red phosphor under the excitation with the wavelength of 395 nm was about 75 mol%. This indicates that the red phosphor has a relatively higher critical concentration than that of the other $Eu^{3+}-doped$ phosphors. The dominant interaction character of $Eu^{3+}$ might be dipole-dipole interaction.

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