한국고분자학회:학술대회논문집 (Proceedings of the Polymer Society of Korea Conference)
- 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
- /
- Pages.275-275
- /
- 2006
Design of Single Ion Conductive Solid Polymer Electrolytes Utilizing the Characteristics of the Boron Atom
- Matsumi, Noriyoshi (Graduate School of Bioagricultural Sciences, Nagoya University) ;
- Ohno, Hiroyuki (Department of Biotechnology, Tokyo University of Agriculture and Technology)
- 발행 : 2006.10.13
초록
A series of organoboron polymer electrolytes were prepared and their ion conductive characteristics was investigated in detail. Alkylborane type polymer electrolytes prepared by hydroboration polymerization exhibited improve lithium transference number due to efficient anion trapping of alkylborane unit. A lithium borate type polymer/salt hybrid was also successfully prepared by dehydrocoupling polymerization of lithium mesitylhydrorate. Ionic conductivity of single ion conductive polymer/salt hybrid was further improved in the case of comb like polymer/boron stabilized imido anion hybrid prepared via polymer reaction of poly(organoboron halide) with hexylamine and PEO monomethylether and subsequent neutralization with lithium hydride.
키워드