Proceedings of the Polymer Society of Korea Conference (한국고분자학회:학술대회논문집)
- 2006.10a
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- Pages.234-234
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- 2006
Unique Photoluminescence Property of a Novel POSS-based Material Having Carbazole
- Imae, Ichiro (Department of Applied Chemistry, Faculty of Engineering, Hiroshima University) ;
- Kawakami, Yusuke (Graduate School of Materials Science, Japan Advanced Institute of Science and Technology [JAIST]) ;
- Fujikawa, Youhei (Department of Applied Chemistry, Faculty of Engineering, Hiroshima University) ;
- Ooyama, Yousuke (Department of Applied Chemistry, Faculty of Engineering, Hiroshima University) ;
- Harima, Yutaka (Department of Applied Chemistry, Faculty of Engineering, Hiroshima University)
- Published : 2006.10.13
Abstract
Novel molecular glassy POSS-based material having carbazole moiety as a photo- and electroactive group was synthesized, and its thermal, morphological, electrochemical, and optical properties were investigated. POSS having carbazole (POSS-Cz) was found to form easily amorphous glassy film by cooling the melt sample or by spin coasting onto glass substrate. POSS-Cz showed monomeric emission even in solid film, which suggests that carbazole moiety can be isolated even in solid state.
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