Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed

유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구

  • 정재욱 (성균관대학교 화학공학과) ;
  • 남우석 (성균관대학교 화학공학과) ;
  • 윤기준 (성균관대학교 화학공학과) ;
  • 이동현 (성균관대학교 화학공학과) ;
  • 한귀영 (성균관대학교 화학공학과)
  • Published : 2006.06.22

Abstract

A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2$-free hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The propane decomposition rate used carbon black N33O as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600{\sim}800^{\circ}C$, paropane gas velocity of $1.0 U_{mf}\;3.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The carbon which was by-product of methane decomposition reaction was deposited on the catalyst surface that was observed by SEM. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

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