A Study on Reactions of $NO_x$, $NO_x$ and $O_3$ Chemistry in an Exhaust Plume under a Stratospheric Condition

Reactions of NO$_{x}$, HO$_{x}$ and $O_3$ chemistry in a diffusion process of the exhaust plume under a stratospheric condition were investigated numerically. Expanding Box method was used to assess the effects of exhaust gases from a stratospheric flight system on $O_3$ depletions. Sensitivity analysis was also performed to identify prime reactions of $O_3$ depletions in an exhaust plume right after the nozzle. In addition, a calculation of reactive flows in stratospheric condition was performed to investigate the characteristics of reactions in a plume. As a result of this study, prime reactions of NO$_{x}$, HO$_{x}$ and $O_3$chemistry in an exhaust plume were identified, and fundamental behavior of chemical species were examined in a exhaust plume.t plume.