대한약학회:학술대회논문집 (Proceedings of the PSK Conference)
- 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2-2
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- Pages.179.2-179.2
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- 2003
Stereoselective Total Synthesis of (-)-Cytoxazone
- Kim, Ji-Duck (College of Pharmacy, Sungkyunkwan University) ;
- Hoon, Jung-Young (College of Pharmacy, Sungkyunkwan University)
- 발행 : 2003.10.01
초록
We have developed the novel one-pot synthetic method for regioselective and stereoselective N-protected amines through the reaction of various ethers with chlorosulfonyl isocyanate (CSI). Also, we found a novel technique to compare directly the stability of carbocations in the solution phase and established the stability order of the various carbocations. And we reported the cleavage of benzyl and p-methoxybenzyl protecting groups of alcohols and phenols in the presence of other functional groups using CSI. (omitted)
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