Synthesis and Characterization of Poly(trimethylene terephthalate) via TPA Process Using Titanium Catalyst

  • Kim, Kap-Jin (Department of Polymer and Fiber Materials Engineering, College of Environment and Applied Chemistry, Kyung Hee University) ;
  • Park, Jung-Il (Department of Polymer and Fiber Materials Engineering, College of Environment and Applied Chemistry, Kyung Hee University) ;
  • Pio Sifuentes (Department of Polymer and Fiber Materials Engineering, College of Environment and Applied Chemistry, Kyung Hee University) ;
  • Lee, Jong-Soon (Department of Polymer and Fiber Materials Engineering, College of Environment and Applied Chemistry, Kyung Hee University)
  • Published : 2003.10.01

Abstract

poly(trimethylene terephthalate) (PTT) was synthesized via condensation polymerization using different molar ratios of 1,3-propane diol (PDO)/terephthalic acid (TPA) in the presence of tetraisopropyl titanate (TiPT) as a polyesterifi-cation catalyst. The effect of reaction conditions on the characteristics of as-polymerized PTT was investigated.

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