Hydrogen purification using membrane reactors

  • Barbieri, Giuseppe (Research Institute on the Membrane Technology, ITM-CNR, Via P. Bucci, c/o University of Calabria) ;
  • Bernardo, Paola (Department of Chemical Engineering and of Materials, University of Calabria) ;
  • Drioli, Enrico (Research Institute on the Membrane Technology, ITM-CNR, Via P. Bucci, c/o University of Calabria/Department of Chemical Engineering and of Materials, University of Calabria) ;
  • Lee, Dong-Wook (KRICT-Membrane and Separation Research Center) ;
  • Sea, Bong-Kuk (KRICT-Membrane and Separation Research Center) ;
  • Lee, Kew-Ho (KRICT-Membrane and Separation Research Center)
  • Published : 2003.07.01

Abstract

Methane steam reforming (MSR) was studied in a membrane reactor (MR) with a Pd-based and a porous alumina membranes. MRs showed methane conversion higher than that foresaw by the thermodynamic equilibrium for a traditional reactor (TR). Silica membranes prepared at KRICT were characterized with permeation tests on single gases ($N_2$, $H_2$ and $CH_4$). These silica membranes can be also used for high temperature applications such as $H_2$ separation $CO_2$ hydrogenation for methanol production is another reaction where $H_2O$ selective removal can be performed with these silica membranes.

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