Electrical Properties by different method of metal complex of G4-48PyP Dendrimer

금속이온 착체방법에 의한 G4-48PyP 덴드리머의 전기적 특성

  • Kim, S.U. (Dept. of Electrical Eng., Dong-A University) ;
  • Jung, S.B. (Dept. of Electrical Eng., Dong-A University) ;
  • Kim, C. (Dept. of Chemistry, Dong-A University) ;
  • Park, J.C. (Dept. of Electronics, Yeongjin Junior College) ;
  • Chang, J.S. (Dept. of Electrical Eng., Kyungil University) ;
  • Kwon, Y.S. (Dept. of Electrical Eng., Dong-A University)
  • Published : 2003.07.21

Abstract

We attempted to fabricate a dendrimer Langmuir-Blodgett(LB) films containing 48 pyridinepropanol functional end group. As the pyridinepropanol functional group could form a complex structure with metal ions. In this study the samples for electrical measurement were fabricated to two types metal complexes with $Pt^{4+}$ ions by LB method. And we have investigated the surface activity at the air-water interface as well as the electrical properties for the monolayers of G4-48PyP dendrimer complex with metal ions($Pt^{4+}$ ions) by different method. In the surface pressure-area(${\pi}$-A) isotherms of the dendrimers, the stable condensed films formed at the air-water interface and the different method of metal complex showed the difference on molecular behavior. We have studied the electrical properties of the ultra thin dendrimer LB films investigated by the current-voltage (I-V) characteristics of metal/dendrimer LB films/metal(MIM) structure. In conclusion, it is demonstrated that the metal ion around G4-48PyP dendrimer can contribute to make formation of network structure among dendrimers and it result from the change of electrical properties.

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