Catalytically Stabilized Combustion Characteristics of Methane on Platinum Catalyst

백금 촉매에 의해 안정화된 메탄의 연소 특성

  • 황철홍 (인하대학교 기계공학과 대학원) ;
  • 정영식 (인하공업전문대학교 기계과) ;
  • 이창언 (인하대학교 기계공학과)
  • Published : 2000.05.26

Abstract

The catalytically stabilized combustion of $CH_4$-air mixture on platinum catalyst was investigated numerically using a 2-D boundary layer model with detailed heterogeneous and homogeneous chemistries. The actual surface site density of monolith coated with platinum was decided by the comparison with experimental data. The comparisons were made between results for cases where only heterogeneous chemistry was allowed and both heterogeneous and homogeneous chemistries were allowed. It was found that the homogeneous reaction in the monolith had little effect on the change of temperature profile, methane conversion rate and light off location. The contributions of each reactions related with CO formation were discussed on the surface. The effects of operation conditions such as equivalence ratio, temperature, velocity and pressure at the entrance were studied. In thermal combustor, CO and NOx was produced less than 1 ppm at the exit and the production of $N_{2}O$ was more dominant than that of NO.

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