The Luminescence Property of Ba-Mg-Al-O:$Eu^2+$ Blue Phosphors

Ba-Mg-Al-O:$Eu^2+$ 청색형광체의 발광특성

  • 김광복 (울산대학교 첨단소재공학부) ;
  • 천희곤 (울산대학교 첨단소재공학부) ;
  • 조동율 (울산대학교 첨단소재공학부) ;
  • 구경완 (영동대학교 정보전자공학부)
  • Published : 2000.11.01

Abstract

Blue phosphor of Ba-Mg-Al-O:Eu$^{2+}$ phase was fabricated by conventional firing techniques under reducing atmosphere and its photoluminescence properties are studied with varying Eu concentration and phost-annealing temperature under air atmosphere. This phosphors were well crystallized with particle size in the range of 3~5um and emitted a blue light at a dominent wavelength 450nm for 254nm UV irradiation. The concentration quenching wit Eu$^{2+}$ was that with increasing Eu concentration the energy transfer between the activator ions steadily improves, so that the excitation energy is transported over larger distances through the lattice before luminescence can occur. Thermal quenching also occurred in this phosphor means that in a host lattice with the $\beta$-alumina structure the bond of an Eu$^{2+}$ ion with the nearest-neighbour oxygen ion is much stronger than in a lattice with the magnetoplumbite structure.cture.

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