The Effects of CdO Addition on the Orientation Process of Bi-Sr-Ca-Cu-O Supercoducting Thick Film

Bi계 초전도 후막의 배향과정에 CdO 첨가의 영향

  • 한영희 (전력연구원 전력계통연구실) ;
  • 성태현 (전력연구원 전력계통연구실) ;
  • 한상철 (전력연구원 전력계통연구실) ;
  • 이준성 (전력연구원 전력계통연구실) ;
  • 정상진 (전력연구원 전력계통연구실)
  • Published : 1999.02.01

Abstract

The orientation mechanism of an amorphous $Bi_{2}$$Sr_{2}$$Ca_{2 x}$$Cd_{x}$$Cu_{3}$$O_{y}$ phase were studied by using the dilatometry. The amorphous $Bi_{2}$$Sr_{2}$$Ca_{2 x}$$Cd_{x}$$Cu_{3}$$O_{y}$ samples brought about a volume shrinkage at the onset of the crystallization of a $Bi_{2}$$Sr_{2}$$CaCu_{2}$$O_{6}$phase around $400^{\circ}C$. The random crystal growth of $Bi_{2}$$Sr_{2}$$CaCu_{2}$$O_{8}$ phase around $800^{\circ}C$. yielded a rapid volume expansion and after then samples shrinmed, accompanied with the crystal orientation. The$Bi_{2}$$Sr_{2}$$Ca_{2 x}$$Cd_{x}$$Cu_{3}$$O_{y}$ (x=0.4) sample exhibited the best-oriented structure because the liquid phase formed seemed to have the lowest viscosity which would contributed to the easy collapse of the card-house structure.

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