Effects of UV light irradiation condition and imidization temperature for the generation of pretilt angle on polyimide surfaces

폴리이미드 표면에서의 프리틸트각 발생에 대한 UV조사 조건과 이미드화온도의 영향

We have investigated the effects of ultraviolet (UV) light irradiation condition and imidization temperature for the generation of pretilt angle in nematic liquid crystal (NLC) on the two kinds of the polyimide (PI) surfaces. High pretilt angle of NLC is generated with oblique p-polarized UV light irradiation of 30$^{\circ}$ on PI surface for 20 min. Also, the high pretilt angle of NLC is generated with oblique p-polarized UV light irradiation of 10-30$^{\circ}$ on PI surface at 20min. The pretilt angle of NLC decreases with increasing the imidization temperature on all rubbed PI surfaces ; the pretilt angle of NLC with oblique p-polarized UV light irradiation of 30$^{\circ}$on PI surface decreases with increasing the imidization temperature. The high pretilt angle of NLC is observed due to high photo-depolymerization reaction by low surface energy at low imidization temperature. We suggest that the pretilt angle of NLC is strongly attributed to the photo-depolymerization reaction with the UV light irradiation condition and imidization temperature.