In hyperspectral remote sensing, linear spectral mixture model is a common procedure decomposing into the components of a mixed pixel and estimating the fraction of each end-member. Although linear spectral mixture model is frequently used in geology and mineral mapping because this model is simple and easy to apply, this model is not always valid in forest and urban area having rather complex structure. This study aims to analyze possible error for applying linear spectral mixture model. For the study, we measured laboratory spectra of mixture sample, having various materials, fractions, distributions. The accuracy of linear mixture model is low with the mixture sample having similar fraction because the multi-scattering between components is maximum. Additionally, this multi-scattering is related to the types, fraction, and distribution of components. Further analysis is necessary to quantify errors from linear spectral mixture model.