The purposes of this study were to verify the longitudinal mediating effects of work-family balance on the relationship of role recognition in the family, marital intimacy and job satisfaction of married women, and to introduce longitudinal mediating effects by using latent growth curve modeling and autoregressive cross-lagged modeling. The subjects were married women from the third year data of the Korean Longitudinal Survey of Women and Family. Structural equational models were conducted with Amos ver. 21.0. The major findings are as follows. First, the result of the longitudinal mediating effects of latent growth modeling is the rate of change of work-family balance mediated between the rate of change of role recognition in the family and the rate of change of job satisfaction, and the rate of change of work-family balance mediated between the rate of change of marital intimacy and the rate of change of job satisfaction. Second, when using the autoregressive cross-lagged modeling, the more role recognition and marital intimacy of third year were the more work-family balance of fourth year, job satisfaction of fifth year. In both models, work-family balance mediated between role recognition in the family, marital intimacy and job satisfaction. Therefore, through this study, mediating effects of work-family balance can be found that there was a longitudinal effects.