• Title, Summary, Keyword: Dye

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One Bath-One Step Dyeing of Nylon-PET Split Type Microfiber (나일론-PET 분할형 극세사의 1욕 1단계 염색)

  • Cho, Hyeon-Tae;Park, Chul-Kwon
    • Textile Science and Engineering
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    • v.46 no.1
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    • pp.23-29
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    • 2009
  • To verify the dyeing behaviors of disperse, acid dye, and metal complex dye on nylon/PET(N/P) split type microfiber in the one bath-one step dyeing, the exhaustion curves of the dyes in single and mixed dye bath were measured under different dyeing temperature and pH of dye bath. Exhaustion behaviors of disperse dye in the one bath dyeing of NIP split type microfiber with disperse dye/acid dye or disperse dye/metal complex dye were not significantly affected by dyeing temperature and pH of dyebath. Acid dye showed high temperature dependency of adsorption-desorption behavior during elevation of dyeing temperature in the one bath dyeing of N/P split type microfiber with disperse dye and acid dye. Metal complex dye in the one bath dyeing of N/P split type microfiber with disperse dye and metal complex dye showed also the temperature dependency of adsorption-desorption, but the final absorption was higher than that of acid dye in the same dyeing conditions and increased with decrease of dyebath pH. The staining of disperse dye on nylon was not effected by dyeing temperature but was decreased with the decrease of pH in the one bath dyeing of N/P split type microfiber.

Fluorescence Quenching Causes Systematic Dye Bias in Microarray Experiments Using Cyanine Dye

  • Jeon, Ho-Sang;Choi, Sang-Dun
    • Genomics & Informatics
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    • v.5 no.3
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    • pp.113-117
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    • 2007
  • The development of microarray technology has facilitated the understanding of gene expression profiles. Despite its convenience, the cause of dye-bias that confounds data interpretation in dual-color DNA microarray experiments is not well known. In order to economize time and money, it is necessary to identify the cause of dye bias, since designing dye-swaps to reduce the dye-specific bias tends to be very expensive. Hence, we sought to determine the reliable cause of systematic dye bias after treating murine macrophage RAW 264.7 cells with 2-keto-3-deoxyoctonate (KDO), interferon-beta $(IFN-{\beta})$, and 8-bromoadenosine (8-BR). To find the cause of systematic dye bias from the point of view of fluorescence quenching, we examined the correlation between systematic dye bias and the proportion of each nucleotide in mRNA and oligonucleotide probe sequence. Cy3-dye bias was highly correlated with the proportion of adenines. Our results support the fact that systematic dye bias is affected by fluorescence quenching of each feature. In addition, we also found that the strength of fluorescence quenching is based on not only dye-dye interactions but also dye-nucleotide interactions as well.

A Study on the One Bath Two Step Dyeing of Nylon/ Cationized Cotton Blends with Acid Dye/Direct Dye (나일론/카티온화 면 혼방품의 산성염료/직접염료에 의한 1욕 2단 염색에 관한 연구)

  • 성우경
    • Textile Coloration and Finishing
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    • v.12 no.1
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    • pp.44-51
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    • 2000
  • The conventional one bath exhaust dyeing system of nylon]/cotton blends with acid dye/direct dye involves a lot of neutral salt which affect dyeability of acid dyes. Because of conventional one bath exhaust dyeing system of nylonl/cotton blends with acid dye/direct dye needs acid dyes adjusted at a neutral liquor, suitable acid dye is limited. To improve dyeing property of nylon/cotton blends, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate dyeing possibilities of nylon/cationized cotton blends with acid dye/direct dye in a non-neutral salt dyebath by one bath two step method. The concentration of direct dye was 1.0%, 0.7%, 0.3%o.w.f. respectively at a non, 1%, 3%owf of reserving agent for being almost equal color strength between nylon and 3% cationized cotton when nylon/3% cationized cotton blends was dyed with acid dye/direct dye at concentration of acid dye(1%o.w.f.) by one bath two step method.

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Electrokinetic Study with Silk Fiber and Acid Dye Solution (견섬유에 대한 산성염료 염색과정에서 계면전기적 성질에 관한 연구)

  • 박인기
    • Textile Science and Engineering
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    • v.18 no.3
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    • pp.47-51
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    • 1981
  • Zeta potential is an important electrical parameter of dyeing process for textile, because it is very rapid and correct method to investigate dyeing phenomena. In order to investigate the surface dyeability and total adsorbed dye amounts of silk fiber with acid dye, zeta potential was measured by streaming dye solution of varying concentrations and electrolyte through the silk fiber, then, after desorption of dye from dyed fiber, total dye amounts was measured by Lambert-Beer method. As the results, the zeta potential was proportional to the amounts of dye adsorbed on silk fiber and the negative zeta potential increased with the amounts of dye adsorbed. Then the zeta potential approaches saturated value. These results were explained on the basis that the dye anions with their negative charge makes salts with NH3+ groups of silk fiber and the formation of hydrogen bond between silk fiber and dye. The surface area of silk fiber covered with the adsorbed dye molecules which was calculated from the reciprocal of slope of relation between the surface dye adsorption and total dye adsorption was much higher than that of nylon fiber.

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Synthesis of Bifunctional Reactive Dyes and Its Dyeability (2 관능성 반응성 염료의 합성 및 그의 염색성)

  • Hong, Sung-Hak;Choi, Chang-Nam;Kim, Sang-Yool
    • Textile Science and Engineering
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    • v.33 no.2
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    • pp.134-139
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    • 1996
  • In order to determine the effects of functional groups of reactive dyes on the dyeability to cotton fabric, bifunctional reactive dyes, which contain the dichlorotriazine/vinylsulfone(DYE-DV) functional groups and the monochlorotriazine/vinylsulfone(DYE-MV) functional groups, were synthesized. The maximum absorption wavelength of ($λ_{max}$DYE-DV and DYE-MV was 512nm and 518nm, and the reaction yields of each dye were 75% and 89%, respectively. The synthesized dyes were compared in terms of the dyeability. The exhaustion amount of DYE-DV was smaller than that of DYE-MV. This means that DYE-DV is more substantive to cotton fiber than DYE-MV. But the fixation amount of DYE-DV was larger than that of DYE-MV at high temperature as well as at low temperature. And the wash-off property of DYE-DV was also better than that of DYE-MV due to its low substantivity.

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Dye-resist Properties of Hetero-multifunctional Dye-resist Agents in Acid Dyeing of Wool

  • Oh Myung-Joon;Koh Joon-Seok;Kim Jae-Pil
    • Fibers and Polymers
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    • v.7 no.2
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    • pp.117-122
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    • 2006
  • The dye-resist effect and leveling properties of hetero-mulifunctional dye-resist agents in acid dyeing of wool were investigated. The dye-resist agent with dichlorotriazinyl group achieved better resist effectiveness than those with monochlo-rotriazinyl group. The resist effectiveness was improved by increasing the number of sulfonate group in dye-resist agents. Also, the resist agents with more sulfonate groups showed better dye-assist effectivness, attributable to the increased electrostatic attraction between dye-resist agents and the cationic dye. However, the leveling properties of dye-resist agents decreased with the number of sulfonate groups in the molecule.

Dye-resist Properties of Reactive Dye-resist Agents in Reactive Dyeing of Silk

  • Park, Sung-Hee;Oh, Myung-Joon;Koh, Joon-Seok
    • Textile Coloration and Finishing
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    • v.19 no.5
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    • pp.8-16
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    • 2007
  • The dye-resist effect of reactive dye-resist agents in reactive dyeing of silk was investigated. The dichlorotriazine-based dye-resists achieved a higher effectiveness than others since they make a charge barrier of diffusion in the silk fiber periphery due to high reactivity of dichlorotriazine group. Similarly, in the case of hetero-multifunctional dye-resist agent, the dye-resist agent containing both a dichlorotriazine and an ${\alpha}$-bromoacrylamide reactive groups achieved better resist effectiveness than those containing both a monochlorotriazine and an ${\alpha}$-bromoacrylamide groups. Also, their resist effectiveness was improved by increasing the number of sulfonate groups in the dye-resist agents and the number of reactive groups in the reactive dyes applied to them.

Dye Adsorption Ability of Chitin in Reactive Dyebath (반응염료염액에서의 키틴의 염료흡착성능)

  • 유혜자;김정희;이혜자;이전숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.2
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    • pp.349-354
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    • 2002
  • In order to decolorize the reactive dye wastewater, we investigated the dye-adsorption ability of chitin, which was natural polymer obtained from shrimp shell. Chitin particle(less than 250 ${\mu}{\textrm}{m}$n) was prepared from shrimp shells in the processes of decalcification in aqueous hydrochloric acid solution and deproteination in aqueous sodium hydroxide solution. The particle size of chitin was controlled to less than 250 ${\mu}{\textrm}{m}$. Three tripes of the reactive dyes-C.I. Reactive Red 120, C.I. Reactive red 241 and C.I. Reactive Black 5-were used. Dye adsorption ability of chitin was investigated by dipping the particle in the dyebaths of concentration of 0.0l%, 0.03% and 0.05% for various periods of time(1,3,5, 10,20,40,80,160minutes). The influence of addition of salt(Na$_2$SO$_4$) and alkali to the dyebaths on dye-absorption was also investigated. We obtained the following results fur the dye-absolution ability of chitin in the dyebaths of three types of reactive dyes. 1) The amount of dye uptake by chitin was increased by addition of salt to the dyebaths. 2) As the concentration of alkali became higher than 3g/I, the amount of dye uptake by chitin was increased. Chitin showed good dye-adsorption ability, when the alkali concentration was high. 3) Chitin showed equal dye uptake in the three types of dyebaths when the dye concentration was 0.0l%. Over 90% of dyestuffs was adsorbed from the dyebaths in ten minutes. When the dye concentration was higher, better adsorption ability was showed in a dye bath of Reactive black 5 than in the others. When the dye concentration was 0.03%, 90% of Reactive red 120 and Reactive red 241 was adsorbed in 40 minutes and the same of Reactive black 5 in 10 minutes. When the dye concentration was 0.05%, 9()% of Reactive red 120 was adsorbed in 80 minutes, and Reactive black 5 in to minutes.

Relationship between the porosity of the nanostructured $TiO_2$ electrode and Dye Loading for Dye-sensitized Solar Cells (염료감응태양전지를 위한 $TiO_2$ 분말 기공도와 염료 흡착량의 관계)

  • Hwang, Seongjin;Jung, Hyunsang;Jeon, Jaeseung;Kim, Hyungsun
    • 한국신재생에너지학회:학술대회논문집
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    • pp.68.2-68.2
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    • 2010
  • Dye-sensitized solar cells (DSSC) show great promise as an inexpensive alternative to conventional p-n junction solar cells. Investigations into the various factors influencing the photovoltaic efficiency have recently been intensified. The conventional absorber electrode in DSSC is composed of compacted or sintered $TiO_2$ nanopowder that carries an anchored organic dye. The absorbance of incident light in the DSC is realized by specifically engineered dye molecules placed on the semiconductor electrode surface ($TiO_2$). The dye absorbs light at wavelengths up to about 920nm, the energy of the exited state of the molecule should be about 1.35eV above the electronic ground state corresponding to the ideal band gap of a single band gap solar cell. The dye molecules ar adhered onto the nanostrutured $TiO_2$ electrode by immersing the sintered electrode into a dye solution, typically 3mM in alcohol, for a long enough period to fully impregnate the electrode. However, the concentrations of the dye is slightly changed due to the evaporation of the alcohol. The dye is more expensive than other materials in DSSC and related to the efficiency of DSSC. Therefore, the concentrations of the dye should be carefully measured. In this study, we investigated to the dye loading on fired $TiO_2$ powder as a function of temperature by the TG-DTA and the dye solution by UV-visible spectroscopy after the impregnation process. The dye loading is related to the porosity of the nanostructured $TiO_2$ electrode.

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High Fastness Dyeing Technology of Polyester Microfiber with Several Disperse Dyes and Vat dye (수종의 분산 염료 및 환원염료에 의한 Polyester microfiber의 고견뢰 염색기술)

  • 백진주;권오대;손아름;이난형;김삼수
    • Textile Coloration and Finishing
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    • v.15 no.6
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    • pp.1-7
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    • 2003
  • Polyester microfiber has usually greater dye uptake than normal denier polyester fiber in same dyeing condition. In spite of this high dye uptake dyed microfiber fabric has not only low visual colour depth but also poor washing fastness property. In order to study high colouring dyeing technology and high washing fastness of polyester microfiber, dyeing property of polyester microfiber was investigated according to the dye solubility and particle size of used disperse dyes in aqueous dye solution. After disperse dyeing, dyed fabric with disperse dye was redyed with a vat dye without reduction clearing in order to obtain a high washing fastness property. The result were as followings ; A small particle sized disperse dyes such as C. I. Disperse Blue 56 and Red 60 showed high rate of initial exhaution compared with a large particle sized disperse dyes like C. I. Disperse Blue 165 and Red 343. In study of dyeing property of polyester microfiber with C. I. Vat Blue 1, polyester microfiber could achieve high dye uptake at a given optimum vatting process conditions. On the other hand, in consecutive dyeing with disperse and vat dye, K/S value of polyester microfiber with a small particle sized disperse dye increased without reduction clearings, but K/S value of polyester microfiber with a large particle sized disperse dye decreased with reduction clearings.