Photocatalytic degradation of methylene blue in aqueous solution using ceramsite coated with micro-Cu2O under visible-light irradiation

  • Li, Tianpeng (College of Environment Science and Engineering, Donghua University) ;
  • Sun, Tingting (School of Basic Medical Science, Wenzhou Medical University) ;
  • Aftab, Tallal Bin (College of Environment Science and Engineering, Donghua University) ;
  • Li, Dengxin (College of Environment Science and Engineering, Donghua University)
  • Received : 2016.08.19
  • Accepted : 2017.02.02
  • Published : 2017.04.01


A novel ceramsite coated with micro-cuprous oxide ($Cu_2O$) catalyst was prepared and its photocatalytic activity was investigated by determining the degradation of methylene blue (MB) in aqueous solutions under Xe light. The results showed that the catalyst had many outstanding characteristics, such as higher BET specific surface area, larger pore size and stronger visible-light adsorption capacity, suggesting that it is a promising photocatalytic material. Under experimental conditions the initial concentration was 15 mg/L, pH was 3 and photocatalyst dosage was 0.5 g, and the degradation rate of MB reached 93.31% after Xe light was irradiated for 75 min. The photocatalytic degradation of MB followed the pseudo-first-order kinetics model, with high correlation coefficient values ($R^2$ >0.95). Some major degradation intermediates and desired products were identified by GC-MS and IC, respectively. Finally, the degradation pathways of MB by the catalyst under Xe light were proposed.


Supported by : Central Universities of China


  1. R. Davide, D. Daniele, F. Maurizio and A. Angelo, Chem. Soc. Rev., 38(7), 1999 (2009).
  2. T. Cetinkaya, L. Neuwirthova, K. M. Kutlakova, V. Tomasek and H. Akbulut, Appl. Surf. Sci., 279, 384 (2013).
  3. Q. Sun, F. Xiao, S. Ren, Z. Dong and X.W. Su, Ceram. Int., 40, 11447 (2014).
  4. C. C. Wang, J.R. Li, X. L. Lv, Y.Q. Zhang and G. S. Guo, Energy Environ. Sci., 7, 2831 (2014).
  5. L. Ren, Z. Jin, W. Wang, H. Liu, J. Lai and J. Yang, Appl. Surf. Sci., 258, 1353 (2011).
  6. A.D. Paola, E. Garcia-Lopez, G. Marci and L. Palmisano, J. Hazard. Mater., 211, 3 (2012).
  7. Y. Li, B. Wang, S. Liu, X. Duan and Z. Hu, Appl. Surf. Sci., 324, 736 (2015).
  8. X. Shen, S. Chen, D. Mu, B. Wu and F. Wu, J. Power Sources, 238, 173 (2013).
  9. A. E. Kasmi, Z.Y. Tian, H. Vieker, A. Beyer and T. Chafik, Appl. Catal. B-Environ., 186(10), 10 (2016).
  10. M.A. Bhosale, T. Sasaki and B. M. Bhanage, Catal. Sci. Technol., 4(12), 4274 (2014).
  11. Y.T. Wang, Y.Q. Pei, W.F. Xiong, T.G. Liu, J. Li and S.L. Liu, Int. J. Biol. Macromol., 81, 477 (2015).
  12. L. Liu, L. Ding, Y. G. Liu, W. J. An, S. L. Lin and Y. H. Liang, Appl. Surf. Sci., 364, 505 (2016).
  13. M.A. Bhosale and B.M. Bhanage, Adv. Powder Technol., 27, 238 (2016).
  14. M.K. Corbierre, N.S. Cameron, M. Sutton, S.G. Mochrie, L.B. Lurio and A. Ruhm, J. Am. Chem. Soc., 123, 10411 (2001).
  15. D.M. Zhang, B. S. Hu, D. J. Guan and Z.T. Luo, Catal. Commun., 76, 7 (2016).
  16. S. Gelover, L. A. Gomez and K. Reyes, Water Res., 40, 3274 (2006).
  17. J. F. Ma, J. F. Ding, L.Y. Li, J. Zou, Y. Kong and K. Sridhar, Ceram. Int., 41, 3191 (2015).
  18. K. Laursen, T. J. White, D. J. Cresswell, P. J. Wainwright and J.R. Barton, J. Environ. Manage., 80(3), 208 (2006).
  19. A.M. Mittelman, D. S. Lantagne, J. Rayner and K.D. Pennell, Environ. Sci. Technol., 49(14), 8515 (2015).
  20. S. Maschio, E. Furlani, G. Tonello, N. Faraone, E. Aneggi and D. Minichelli, Waste Manage., 29(11), 2880 (2009).
  21. Y.Z. Zhuang, C.Y. Chen and T. Ji, Constr. Build. Mater., 46, 13 (2013).
  22. E. Furlani, G. Tonello, S. Maschio, E. Aneggi, D. Minichelli and S. Bruckner, Ceram. Int., 37, 1293 (2011).
  23. C. Wang and F. S. Zhang, Mater. Lett., 93, 380 (2013).
  24. A. Larbot, M. Bertrand, S. Marre and E. Prouzet, Sep. Purif. Technol., 32, 81 (2003).
  25. Y.X. Zhao, Y. N. Yang, S. J. Yang, Q. H. Wang, C. P. Feng and Z.Y. Zhang, J. Colloid Interface Sci., 393, 264 (2013).
  26. C. Jiang, L.Y. Jia, B. Zhang, Y.L. He and K. George, J. Environ. Sci., 26, 466 (2014).
  27. Y. Shi, K. Sun, X.B. Qi and Q. Gao, J. Wuhan University Technol. - Mater. Sci. Ed., 30(3), 649 (2015).
  28. Y. Cheng, W. J. Fan and L. Guo, Sep. Purif. Technol., 130, 167 (2014).
  29. M. Wegmann, B. Michen, T. Luxbacher, J. Fritsch and T. Graule, Water Res., 42(6), 1726 (2008).
  30. Y. Zhang, F. He, S. B. Xia, L.W. Kong, D. Xu and Z.B. Wu, Ecol. Eng., 64, 186 (2014).
  31. S. Qiu, X. Huang, S.W. Xu and F. Ma, Appl. Biochem. Biotechnol., 176, 267 (2015).
  32. T. P. Li, T.T. Sun and D. X. Li, J. Mater. Cycles Waste Manage., DOI:10.1007/s10163-016-0547-3.
  33. T. P. Li, T.T. Sun and D.X. Li, Desalin. Water Treat., DOI:10.5004/ dwt.2016.0239.
  34. Z. Hosseinpour, A. Alemi, A.A. Khandar, X. Zhao and Y. Xie, New J. Chem., 39(7), 5470 (2015).
  35. H. H. Liu, Q.Y. Chen, Y. Yu, Z. H. Liu and G. Xue, J. Hazard. Mater., 263(2), 593 (2013).
  36. W.X. Zou, L. Zhang, L.C. Liu, X. B. Wang, J. F. Sun and S.G. Wu, Appl. Catal. B-Environ., 181, 495 (2016).
  37. D. H. Guo, L. X. Wang, Y. J. Du, Z.Q. Ma and L. Shen, Mater. Lett., 160, 541 (2015).
  38. B. Qin, Y. B. Zhao, H. Li, L. Qiu and Z. Fan, Chinese J. Catal., 36, 1321 (2015).
  39. S.N. Basahel, T. T. Ali, M. Mokhtar and K. Narasimharao, Nanoscale Res. Lett., 10, 73 (2015).
  40. J. S. Valente, F. Tzompantzi, J. Prince, J. G. H. Cortez and R. Gomez, Appl. Catal. B-Environ., 90, 330 (2009).
  41. Y.Y. Xu, X. L. Jiao and D.R. Chen, J. Phys. Chem. C, 112(43), 16769 (2008).
  42. C. H. Cao, L. Xiao, C. H. Chen and Q. H. Cao, Appl. Surf. Sci., 357, 1171 (2015).
  43. W. Subramonian and T.Y. Wu, Water Air Soil Poll., 225(40), 1922 (2014).
  44. Omer Sahin, M. Kaya and C. Saka, Appl. Clay Sci., 116, 46 (2015).
  45. Y.D. Luo, Q.Q. Huang, B. Li, L. H. Dong, M.G. Fan and F.Y. Zhang, Appl. Surf. Sci., 357, 1072 (2015).
  46. O. Ozdemir, M. Turan, A.Z. Turan, A. Faki and A.B. Engin, J. Hazard. Mater., 166, 647 (2009).
  47. D. Zhao, G. Sheng, C. Chen and X. Wang, Appl. Catal. B-Environ., 111, 303 (2012).
  48. F.C.F. Low, T.Y. Wu, C.Y. Teh, J.C. Juan and N. Balasubramaniam, Color Technol., 128(1), 44 (2012).
  49. P. Dumrongrojthanath, A. Phuruangrat, P. Junploy, S. Thongtem and T. Thongtem, Res. Chem. Intermediat., 42, 1651 (2016).
  50. J.K. Dong, H.Y. Xu, F. J. Zhang, C. Chen, L. Liu and G.T. Wu, Appl. Catal. A-Gen., 470, 294 (2014).
  51. D. Gumus and F. Akbal, Water Air Soil Poll., 216, 117 (2011).
  52. R. S. Dariani, A. Esmaeili, A. Mortezaali and S. Dehghanpour, Optik, 127, 7143 (2016).
  53. Q. Wang, S.L. Tian and P. Ning, Ind. Eng. Chem. Res., 53, 643 (2014).