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Synthesis and Characterization of Red Organic Phosphor for Hybrid LED

Hybrid LED용 적색 유기형광체의 합성 및 특성 연구

  • Lee, Seung Min (Department of LED Convergence Lighting for Shipbuilding, Pukyong National University) ;
  • Jeong, Yeon Tae (Department of LED Convergence Lighting for Shipbuilding, Pukyong National University)
  • 이승민 (부경대학교 LED융합공학전공) ;
  • 정연태 (부경대학교 LED융합공학전공)
  • Received : 2016.09.30
  • Accepted : 2016.11.03
  • Published : 2017.01.01

Abstract

We report the studies on the red organic phosphor by using perylene bisimide derivatives. Even though perylene bisimide derivatives have excellent thermal stability and luminous efficiency, they have low solubility in organic solvents. In this research, modified perylene bisimide derivative, N,N'-Bis(4-bromo-2, 6-diisopropylphenyl)-1, 6, 7, 12-tetraphenoxyperylene-3, 4, 9, 10-tetracarboxyl bisimide (1C), has been prepared by the reaction of phenol with N,N'-Bis(4-bromo-2, 6-diisopropylphenyl)-1, 6, 7, 12-tetrachloroperylene-3, 4, 9, 10-tetracarboxyl bisimide (1B) in presence of DMF, at $70^{\circ}C$. The synthesized (1C) was characterized by using $^1H-NMR$, FT-IR, UV/V is spectroscopy, and TGA. The absorbtion and emission of (1C) was shown at 576 nm and 610 nm in UV/V is spectrum. In TGA thermogram, (1C) showed good thermal stability without significant weight loss to $220^{\circ}C$. And in the solubility analysis, (1C) with phenoxy group showed the good solubility in general organic solvents. The blended films of (1C) with PMMA (polymethyl methacrylate) at different weight % concentration such as 10, 5, 1 weight % have been prepared. The blended film was shown at 616 nm when monitored at 450 nm in PL emission spectra.

Acknowledgement

Grant : 조선.해양플랜트.해양환경 LED융합조명 핵심기술개발 전문인력양성

Supported by : 산업통상자원부

References

  1. G. Singh and D. S. Mehta, J. Opt., 15, 2040 (2013). [DOI: https://doi.org/10.1088/2040-8978/15/2/025710] https://doi.org/10.1088/2040-8978/15/2/025710
  2. S. B. Raut, S. J. Dhoble, and R. G. Atram, Adv. Mat. Lett, 2, 373 (2011). [DOI: https://doi.org/10.5185/amlett.2011.3075am2011] https://doi.org/10.5185/amlett.2011.3075am2011
  3. J. Choi, C. Sakong, J. H. Choi, C. Yoon, and J. P. Kim, Dyes and Pigments, 90, 82 (2011). [DOI: https://doi.org/10.1016/j.dyepig.2010.11.006] https://doi.org/10.1016/j.dyepig.2010.11.006
  4. E. Kozma, W. Mroz, and F. Galeotti, Dyes and Pigment, 114, 138 (2015). [DOI: https://doi.org/10.1016/j.dyepig.2014.11.009] https://doi.org/10.1016/j.dyepig.2014.11.009
  5. Z. Yuan, J. Li, Y. Xiao, Z. Li, and X. Qian, J. Org. Chem., 75, 3007 (2010). [DOI: https://doi.org/10.1021/jo100231j] https://doi.org/10.1021/jo100231j
  6. K. Baek and Y. T. Jeong, J. Korean Inst. Electr. Electron. Mater. Eng., 25, 140 (2012). [DOI: http://dx.doi.org/10.4313/JKEM.2012.25.2.140]
  7. K. S. Park and Y. T. Jeong, J. Korean Inst. Electr. Electron. Mater. Eng., 24, 398 (2011). [DOI: 10.4313/JKEM.2011.24.5.398]
  8. C. Fan and C. Yang, Chem. Soc. Rev., 43, 6439 (2014). [DOI: https://doi.org/10.1039/C4CS00110A] https://doi.org/10.1039/C4CS00110A
  9. P. Wehrmann and S. Mecking, Oranometallics, 27, 1399 (2008). [DOI: https://doi.org/10.1021/om700942z https://doi.org/10.1021/om700942z
  10. W. G. Choi and Y. T. Jeong, J. Korean Inst. Electr. Electron. Mater. Eng., 26, 528 (2013). [DOI: http://dx.doi.org/10.4313/JKEM.2013.26.7.528]
  11. C. Zhao, Y. Zhang, R. Li, X. Li, and J. Jiang, J. Org. Chem, 72, 2402 (2007). [DOI: https://doi.org/10.1021/jo062150j] https://doi.org/10.1021/jo062150j