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Synthesis of Propylene Carbonate over Metal containing Ionic Liquid Catalysts

금속 함유 이온성 액체 촉매상에서의 프로필렌 카보네이트의 합성

  • Moon, Ye-Ji (Chemical Industry Development Center, Korea Research Institute of Chemical Technology) ;
  • Ji, Dahye (Chemical Industry Development Center, Korea Research Institute of Chemical Technology) ;
  • Kim, Dong-Woo (Chemical Industry Development Center, Korea Research Institute of Chemical Technology) ;
  • Kim, Hyeon-Gook (Chemical Industry Development Center, Korea Research Institute of Chemical Technology) ;
  • Cho, Deug-Hee (Chemical Industry Development Center, Korea Research Institute of Chemical Technology)
  • 문예지 (화학산업고도화센터 한국화학연구원) ;
  • 지다혜 (화학산업고도화센터 한국화학연구원) ;
  • 김동우 (화학산업고도화센터 한국화학연구원) ;
  • 김현국 (화학산업고도화센터 한국화학연구원) ;
  • 조득희 (화학산업고도화센터 한국화학연구원)
  • Received : 2015.11.30
  • Accepted : 2015.12.29
  • Published : 2016.04.10

Abstract

In this study, three different metal-containing ionic liquid catalysts were prepared by metal insertion and characterized by various physicochemical analytic methods. The catalytic performance of the metal containing ionic liquids in the cycloaddition of $CO_2$ with propylene oxide (PO) to produce propylene carbonate (PC) was investigated under the solvent free condition. The order of approximate rate constants ($K_{app}$) for the metal containing ionic liquid catalysts was $(MeIm)_2ZnCl_2$, > $(MeIm)_2FeCl_2$ > $(MeIm)_2CuCl_2$. These results are in accord with the experimentally obtained activity order of the different metal containing ionic liquid catalysts.

Acknowledgement

Supported by : 한국화학연구원

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