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Biomimetic Copper Complex Containing Polymer Modified Electrode for Electrocatalytic Reduction of Oxygen

  • Received : 2016.10.28
  • Accepted : 2016.12.12
  • Published : 2016.12.31

Abstract

The development of non-precious metal based electrocatalysts is highly desired for the oxygen reduction reaction (ORR) as alternates to noble metal based ORR electrocatalysts. Herein, we report mononulcear copper(II) complex $[CuLbpy]ClO_4$ (L=4-[(2-hydroxyphenylimino)methyl]benzoic acid) containing poly(allylamine.HCl) polymer (PAlACuLbpy) as an electrocatalyst for oxygen reduction reaction (ORR). PAlACuLbpy was mixed with poly(acrylic acid) and tetraethylortho silicate to prepare a composite and then deposited on the screen printed electrode surface. The modified electrode (PAlACuLbpy/PCE) is highly stable and showed a quasi-reversible redox behavior with $E_{1/2}=-0.2V$ vs. Ag/AgCl(3 M KCl) in 0.1 M phosphate buffer at pH 7 under argon atmosphere. PAlACuLbpy/PCE exhibited a remarkable ORR activity with an onset potential of -0.1 V vs Ag/AgCl in 0.1 M PB (pH 7) in the presence of oxygen. The kinetics for ORR was studied by rotating disk voltammetry in neutral aqueous medium and the results indicated that the number of electrons involving in the ORR is four and the conversion products are water and hydrogen peroxide.

Acknowledgement

Supported by : Korea Institute of Energy Technology Evaluation and Planning (KETEP)

References

  1. E. I. Solomon, U. M. Sundaram, T. E. Machonkin, Chem. Rev., 1996, 96(7), 2563-2606. https://doi.org/10.1021/cr950046o
  2. L. Que Jr., Y. Watanabe, Science 2001, 292(5517), 651-653. https://doi.org/10.1126/science.1059941
  3. E. I. Solomon, P. Chen, M. Metz, S.K. Lee, A. E. Palmer, Angew. Chem. Int. Ed., 2001, 40(24), 4570-4590. https://doi.org/10.1002/1521-3773(20011217)40:24<4570::AID-ANIE4570>3.0.CO;2-4
  4. R. H. Holm, P. Kennepohl, E. I. Solomon, Chem. Rev., 1996, 96(7), 2239-2314. https://doi.org/10.1021/cr9500390
  5. I. E. Marko, M. Tsukazaki, P. R. Giles, S. M. Brown, C. J. Urch, Angew. Chem. Int. Ed., 1997, 36(20), 2208-2210. https://doi.org/10.1002/anie.199722081
  6. E. I. Solomon, P. M. Jones, J. A. May, Chem. Rev., 1993, 93(8), 2623-2644. https://doi.org/10.1021/cr00024a003
  7. E. I. Solomon, F. Tuczek, D. E. Root, C. A. Brown, Chem. Rev., 1994, 94(3), 827-856. https://doi.org/10.1021/cr00027a013
  8. S.B. Adler, Chem. Rev., 2004, 104(10), 4791-4844. https://doi.org/10.1021/cr020724o
  9. J.W. Shie, U. Yogeswaran, S. Chen, Talanta 2009, 78(3), 896-902. https://doi.org/10.1016/j.talanta.2008.12.063
  10. N. Mano, V. Soukharev, A. Heller, J. Phys. Chem. B, 2006, 110(23), 11180-11187. https://doi.org/10.1021/jp055654e
  11. G. Merle, A. Habrioux, K. Servat, M. Rolland, C. Innocent, K.B. Kokoh, S. Tingry, Electrochim. Acta 2009, 54(11), 2998-3003. https://doi.org/10.1016/j.electacta.2008.12.017
  12. V. Soukharev, N. Mano, A. Heller, J. Am. Chem. Soc., 2004, 126(27), 8368-8369. https://doi.org/10.1021/ja0475510
  13. C.W.B. Bezerra, L. Zhang, H. Liu, K. Lee, A.L.B. Marques , E. P. Marques, H. Wang, J. Zhang, J. Power Sources 2007, 173, 891-908. https://doi.org/10.1016/j.jpowsour.2007.08.028
  14. M. A. Rigsby, W.P. Zhou, A. Lewera, H.T. Duong, P.S. Bagus, W. Jaegermann, R. Hunger, A. Wieckowski, J. Phys. Chem. C, 2008, 112(39), 15595-15601. https://doi.org/10.1021/jp805374p
  15. M. Broring, Angew. Chem. Int. Ed., 2007, 46(33), 6222-6224. https://doi.org/10.1002/anie.200702254
  16. Z. Varpness, J. W. Peters, M. Young, T. Douglas Nano Lett., 2005, 5(11), 2306-2309. https://doi.org/10.1021/nl0517619
  17. R. Reslow, Acc. Chem. Res., 1995, 28(3), 146-153. https://doi.org/10.1021/ar00051a008
  18. T. Punniyamurthy, S. Velusamy, J. Iqbal Chem. Rev., 2005, 105(6), 2329-2364. https://doi.org/10.1021/cr050523v
  19. V. Artero, M. Fontecave, Coord. Chem. Rev., 2005, 249(15), 1518-1535. https://doi.org/10.1016/j.ccr.2005.01.014
  20. Y. Feng, N. Alonso-Vante, Phys. Stat. Sol. (b), 2008, 245(9), 1792-1806. https://doi.org/10.1002/pssb.200879537
  21. R. Bashyam, P. Zelenay, Nature 2006, 443(7107), 63-66. https://doi.org/10.1038/nature05118
  22. M.A. Thorseth, C.E. Tornow, E.C.M. Tse, A.A. Gerwith, Coord. Chem. Rev., 2013, 257(1), 130-139. https://doi.org/10.1016/j.ccr.2012.03.033
  23. F.F. Wang, P.J. Wei, G.Q. Yu, J.G. Liu, Chem. Eur. J., 2016, 22(1), 382-389. https://doi.org/10.1002/chem.201502589
  24. R. C. Wang, T.L. Yin, P.J. Wei, J.G. Liu, RSC Adv., 2015, 5(81), 66487-66493. https://doi.org/10.1039/C5RA12972A
  25. Y.T. Xi, P.J. Wei, R.C. Wang, J.G. Liu, Chem. Commun., 2015, 51(35), 7455-7458. https://doi.org/10.1039/C5CC00963D
  26. J. Zhang, F.C. Anson, J. Electroanal. Chem., 1993, 348(1), 81-97. https://doi.org/10.1016/0022-0728(93)80124-Z
  27. J. Zhang and F.C. Anson, J. Electroanal. Chem., 1992, 331(1-2), 945-957. https://doi.org/10.1016/0022-0728(92)85016-V
  28. K. Slowinski, Z. Kublik, R. Bilewicz, M. Pietraszkiewicz J. Chem. Soc., Chem. Commun., 1994, 9, 1087-1088.
  29. V.L.N. Dias, E.N. Fernandes, L.M.S. da Silva, E. P. Marques, J. Zhang, A.L. B. Marques, J. Power Sources 2005, 142(1), 10-17. https://doi.org/10.1016/j.jpowsour.2004.09.032
  30. C. X. Cai, K. H. Xue, X. Y. Xu, Q. H. Luo, J. Appl. Electrochem., 1997, 27(7), 793-798. https://doi.org/10.1023/A:1018416610935
  31. Y. Lei, F. C. Anson, Inorg. Chem., 1995, 34(5), 1083-1089. https://doi.org/10.1021/ic00109a014
  32. C. C. L. McCrory, X. Ottenwaelder, T. D. P. Stack, C. E. D. Chidsey, J. Phys. Chem. A, 2007, 111(49), 12641-12650. https://doi.org/10.1021/jp076106z
  33. M. Boopathi, M. S. Won, Y. H. Kim, S. C. Shin, Y.B. Shim, J. Electrochem. Soc., 2002, 149(7), E265-E271. https://doi.org/10.1149/1.1482769
  34. M.S. Thorum, J. Yadav, A.A. Gewirth, Angew. Chem. Int. Ed., 2009, 121, 171. https://doi.org/10.1002/ange.200803554
  35. A. Heller, Curr. Opin. Chem. Biology, 2006, 10(6), 664-672. https://doi.org/10.1016/j.cbpa.2006.09.018
  36. J. Ribas, C. Diaz, R. Costa, J. Tercero, X. Solans, M. Font-Bardia, H. Stoeckli-Evans, Inorg. Chem., 1998, 3, 7233.
  37. K. Vaik, D.J. Schiffrin, K. Tammeveski, Electrochem. Commun. 2004, 6(1), 1-5. https://doi.org/10.1016/j.elecom.2003.10.003
  38. J.J. Zhang, F.C. Anson, Electrochim. Acta 1993, 38(16), 2423-2429. https://doi.org/10.1016/0013-4686(93)85111-B