Development of Analytical Method and Monitoring of Organophosphorus Pesticides in the Raw Water and Clean Water by Liquid Chromatography-Tandem Mass Spectrometry

LC/MS/MS를 이용한 유기인계 농약류의 최적 분석법 정립과 원·정수에서의 모니터링

  • 김경아 (부산광역시 상수도사업본부 수질연구소) ;
  • 송미정 (부산광역시 상수도사업본부 수질연구소) ;
  • 염훈식 (부산광역시 상수도사업본부 수질연구소) ;
  • 손희종 (부산광역시 상수도사업본부 수질연구소) ;
  • 이상원 (부산광역시 상수도사업본부 수질연구소) ;
  • 최진택 (부산광역시 상수도사업본부 수질연구소)
  • Received : 2015.05.15
  • Accepted : 2015.11.26
  • Published : 2015.12.29


The analytical method for 16 organophosphorus pesticides was developed in this study. The 16 organophosphorus pesticides were analyzed by liquid chromatography-tandem mass spectrometry (LC/MS/MS) using on-line solid phase extraction (on-line SPE) with PLRP- S cartridge. Analysis of all analytes in the MS/MS was processed in the electrospray ioni-zation (ESI) positive mode. They are Azinphos ethyl, Chlorfenvinphos, Ethion, Famphur, Phosmet, Phosphamidon, Terbufos, Aspon, Chlorpyrifos-methyl, Crotoxyphos, Dichlofenthi-on, Dicrotophos, Fonofos, Thionazin, Dimethoate and Iprobenfos. Limits of detection (LODs) and Limits of quantification(LOQs) were obtained as 0.8~2.0 ng/L and 2.6~6.4 ng/L, respectively. All compounds were not detected at the 8 sampling points of the raw water and clean water.


Organophosphorus pesticides;Liquid chromatography-tandem mass spectrometry;On-line solid phase extraction;Electrospray ionization;Azinphos ethyl


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