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The Study of Ibuprofen Degradation Properties by Combination of Wave Energy (Ultrasound, Ultraviolet) and Persulfate Ion

파 에너지 (자외선, 초음파)/과황산나트륨을 이용한 이부프로펜 분해특성 연구

  • Na, Seungmin (Department of Civil Environmental and Architecture, Korea University) ;
  • Ahn, Yungyong (Korea Basic Science Institute) ;
  • Cui, Mingcan (Department of Civil Environmental and Architecture, Korea University) ;
  • Son, Younggu (Department of Civil Environmental and Environmental Engineering, Kumoh National Institute of Technology) ;
  • Khim, Jeehyeong (Department of Civil Environmental and Architecture, Korea University)
  • 나승민 (고려대학교 건축사회환경공학과) ;
  • 안윤경 (한국기초과학지원연구원, 서울센터 분석연구부) ;
  • ;
  • 손영규 (금오공과대학교 토목환경공학과) ;
  • 김지형 (고려대학교 건축사회환경공학과)
  • Received : 2013.08.07
  • Accepted : 2014.04.18
  • Published : 2014.05.30

Abstract

In this study, ibuprofen(IBP) degradation by the photochemical ($UV/S_2O{_8}^{2-}$) and sonochemical ($US/S_2O{_8}^{2-}$) processes was examined under various parameters, such as UV ($10{\sim}40{\pm}5W/L$) and US ($50{\sim}90{\pm}5W/L$) power density, optimum dosage of persulfate ion ($S_2O{_8}^{2-}$), temperature ($20{\sim}60^{\circ}C$) and anions effect ($Cl^-$, $HCO_3{^-}$, $CO{_3}^{2-}$). The pseudo-first-order degradation rate constants were in the order of $10^{-1}$ to $10^{-5}min^{-1}$ depending on each processes. The synergistic effect of IBP degradation in $UV/S_2O{_8}^{2-}$ and $US/S_2O{_8}^{2-}$ processes could investigated, due to the generation of $SO_4{^-}$ radical. This result can confirm from the produced $H_2O_2$ and $SO{_4}^{2-}$ concentration in each processes. IBP degradation rate affected by the $S_2O{_8}^{2-}$ dosage, temperature, power and anion existence parameters. In particular, IBP degradation rate increased with the increase of the temperature ($60^{\circ}C$) and applied power density (UV:$40{\pm}5W/L$, US:$90{\pm}5W/L$). On the other hand, anions effect on the IBP degradation was negative, due to the anion play as a the scavenger of radical.

Keywords

Ibufropen;Sonochemistry;Photochemistry;Persulfate;Radical

Acknowledgement

Supported by : 한국연구재단

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