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UV Curing and Peeling Characteristics of Acrylic Coating Ink with Various Amounts of Photoinitiator, Oligomer and Talc

광개시제, 올리고머 그리고 Talc 함량에 따른 아크릴계 코팅제의 UV경화 및 박리특성

  • Yang, Jee-Woo (Department of Chemical & Biological Engineering/Chemical Materials Commercialization RIC, Hanbat National University) ;
  • Seo, Ah Young (Department of Chemical & Biological Engineering/Chemical Materials Commercialization RIC, Hanbat National University) ;
  • Lee, Chul Woo (Department of Chemical & Biological Engineering/Chemical Materials Commercialization RIC, Hanbat National University)
  • 양지우 (한밭대학교 화학생명공학과/화학소재상용화지역혁신센터(RIC)) ;
  • 서아영 (한밭대학교 화학생명공학과/화학소재상용화지역혁신센터(RIC)) ;
  • 이철우 (한밭대학교 화학생명공학과/화학소재상용화지역혁신센터(RIC))
  • Published : 2013.10.31

Abstract

As the usuage of tempered glass for touch panel increased rapidly with the development of industry, the amount of UV curable coating solution used to protect glass surfaces during a tempered glass manufacturing process increased as well. The UV curable coating has advantages compared to thermal curing such as shortened curing time and non-solvent. Appropriated polymer and monomer were used as an acid polymer to grant an alkali peeling ability. The monomers were 2-hydroxyl methylacrylate, 1,6-hexanediol diacrylate and dipentaerythritol hexaacrylate which have acryl groups of 1, 2, and 6, respectively. The combination of three different types of photoinhibitors were used and bisphenol A epoxy diacrylate was used as an oligomer. In this study, experiments were carried out by controlling the amount of photoinitiator, oligomer, and additive while maintaining the constant content of the acid polymer and the acrylic monomer. The changes in physical properties according to the additive content were investigated. It was found that the combination of photoinitiators was necessary to achieve the hardness above 4H and it was possible to control the delamination type of the coating film from a sheet to pieces by the addition of TPO as an initiator. The increase in oligomer contents increased the hardness and adhesiveness alongside dissection time. Talc content of 20 wt% showed the best results.

References

  1. J. Z. Wicks, F. N. Jones, S. P. Pappas, and D. A. Wicks, Organic Coatings : Science and Technology, John Wiley & Sons Inc., 1, 574, Honoke, New Jersey (2007).
  2. B. Muller and U. Poth, Coatings Formulation, Vincentz, 1, 237, Hannover (2006).
  3. C. G. Roffey, Photogeneration of Reactive Species for UV Curing, John Wiley & Sons Inc., 1, Chichester, New York (1997).
  4. J. P. Fouassier, Photoinitiated Polymerization : Theory and Applications, Rebecca Dolbey, 9, Rapra Technology Ltd., U.K. (1998).
  5. G. Orcel, S. Vanpoulle, J. Y. Barraud, J. Y. Boniort, and B. Overton, Wire, 46, 206 (1996).
  6. A. H. Rodas, R. E. S. Bretas, and A. Reggianni, J. Mater. Sci., 21, 3025 (1986). https://doi.org/10.1007/BF00553332
  7. C. M. Ryu, Y. H. Nam, S. H. Lee, H. I. Kim, D. H. Lim, H. J. Kim, and K. M. Kim, J. Adhes. Interf., 10, 134 (2009).
  8. M. Nakazawa, J. Adh. Soc. Jap., 36, 28 (2000).
  9. H. Guo, A. E. Hamielec, and S. Zhu, J. Appl. Polym. Sci., 66, 935 (1997). https://doi.org/10.1002/(SICI)1097-4628(19971031)66:5<935::AID-APP14>3.0.CO;2-M
  10. M. Braithwaite, S. Davidson, R. Holman, C. Lowe, M. S. Salim, C. Wall, and P. K. T. Oldring, Chemistry & Technology of UV & EB Formulation for Coatings, Inks & Paints, P. K. T. Oldring, SITA Technology, London (1991).
  11. J. C. Jung, Polymer (Korea), 10, 570 (1986).
  12. C. E. Hoyle and J. F. Kinstle, Anal. Chem., 62, 719A (1990). https://doi.org/10.1021/ac00212a730
  13. V. B. Missovicc-Stankovicc, M. D. Maksimovicc, Z. Kaccarevicc-Popovicc, and J. B. Zotovicc, Prog. Org. Coat., 33, 68 (1998). https://doi.org/10.1016/S0300-9440(98)00011-3
  14. K. J. Mintz, Thermochim. Acta, 392, 243 (2002).
  15. J. W. Hong, H. K. Kim, J. A Yu, and Y. B. Kim, J. Appl. Polym. Sci., 84, 132 (2002). https://doi.org/10.1002/app.10273