Evaluation of the Giggenbach Bottle Method with Artificial Fumarolic Gases

인공 분기공 가스를 이용한 Giggenbach bottle 법의 평가

  • Lee, Sangchul (Department of Geological Sciences, Pusan National University) ;
  • Kang, Jungchun (Department of Geological Sciences, Pusan National University) ;
  • Yun, Sung Hyo (Department of Earth Science Education, Pusan National University) ;
  • Jeong, Hoon Young (Department of Geological Sciences, Pusan National University)
  • Received : 2013.11.20
  • Accepted : 2013.12.02
  • Published : 2013.12.31


We aimed to evaluate the effectiveness of the Giggenbach bottle method and develop the related pretreatment and analytical methods using artificial fumarolic gases. The artificial fumarolic gases were generated by mixing $CO_2$, CO, $H_2S$, $SO_2$, $H_2$, and $CH_4$ gas streams with a $N_2$ stream sparged through an acidic medium containing HCl and HF, with their compositions varied by adjusting the gas flow rates. The resultant fumarolic gases were collected into an evacuated bottle partially filled with a NaOH absorption solution. While non-condensible gases such as CO, $H_2S$, and $CH_4$ accumulated in the headspace of the bottle, acidic components including $CO_2$, $SO_2$, HCl, and HF that were dissolved into the alkaline solution. Like other acidic components, $H_2S$ also dissolved into the solution, but it reacted with dissolved $Cd^{2+}$ to precipitate as CdS when $Cd(CH_3COO)_2$ was added. The non-condensible gases were analyzed on a gas chromatography. Then, CdS precipitates were separated from the alkaline solution by filtration, and they were pretreated with $H_2O_2$ to oxidize CdS-bound sulfide into sulfate. In addition, a portion of the solution was also pretreated with $H_2O_2$ to oxidize sulfite to sulfate. Following the pretreatment, the resultant samples were analyzed for $SO_4^{2-}$, $Cl^-$ and $F^-$ on an ion chromatography. In the meanwhile, dissolved $CO_2$ was analyzed on a total organic carbon-inorganic carbon analyzer without such pretreatment. According to our experimental results, the measured concentrations of the fumarolic gases were shown to be proportional to the gas flow rates, indicating that the Giggenbach bottle method is adequate for monitoring volcanic gas. The pretreatment and analytical methods employed in this study may also enhance the accuracy and reproducibility of the Giggenbach bottle method.


Supported by : 기상청


  1. Fischer, T.P., Arehart, G.B., Sturchio, N.C., and Williams, S.N., 1996, The relationship between fumarole gas composition and eruptive activity at Galeras Volcano, Columbia. Geology, 24, 531-534.<0531:TRBFGC>2.3.CO;2
  2. Gerlach, T.M. and Casadevall, T.J., 1986, Fumarole emissions at Mount St. Helens volcano, June 1980 to October 1981: Degassing of a magma-hydrothermal system. Volcanology and Geothermal Research, 28, 141-160.
  3. Giggenbach, W.F., 1975, A simple method for the collection and analysis of volcanic gas samples. Bulletin of Volcanology, 39, 15-27.
  4. Giggenbach, W.F. and Matsuo, S., 1991, Evaluation of results from second and third IAVCEI field workshop on volcanic gases, Mt Usu, Japan, and White Island, New Zealand. Applied Geochemistry, 6, 125-141.
  5. Giggenbach, W.F., Tedesco, D., Sulistiyo, Y., Caprai, A., Cioni, R., Favara, R., Fischer, T.P., Hirabayashi, J.I., Korzhinsky, M., Martini, M., Menyailov, I., and Shinohara, H., 2001, Evaluation of results from the fourth and fifth IAVCEI field workshop on volcanic gases, Vulcano island, Italy, and Java, Indonesia. Volcanology and Geothermal Research, 108, 157-172.
  6. Halmer, M.M., Schmincke, H.U., and Graf, H.F., 2002, The annual volcanic gas input into the atmosphere, in particular into the stratosphere: A global data set for the past 100 years. Volcanology and Geothermal Research, 115, 511-528.
  7. Jiang, Z., Yu, S., Yoon S.M., and Choi, K.H., 2013, Damage and socio-economic impact of volcanic ash. Korean Earth Science Society, 34, 536-549.
  8. Kiyosu, Y. and Okamoto, Y., 1998, Variation in fumarolic H2 gas and volcanic activity at Nasudake in Japan. Volcanology and Geothermal Research, 80, 27-37.
  9. Lee, C.G., Lee, H.L., Hong, C.S., Jeung, J.S., Park J.E., and Kim Y.J., 2005, Remote sensing of volcanic gases using multi axis differential optical absorption spectroscopy. Korean Society of Environmental Engineers Spring Conference, 489-492. (in Korean)
  10. Lee, S.Y., Lee, S.C., Yang, K.H., and Jeong, H.Y., 2012, A technical note on monitoring methods for volcanic gases. The Petrological Society of Korea, 21, 415-429. (in Korean)
  11. Luong, J., Gras, R., Cortes, H.J., and Shellie, R.A., 2013, Multidimensional gas chromatography for the characterization of permanent gases and light hydrocarbons in catalytic cracking process. Chromatography A, 1271, 185-191.
  12. Mioduszewski, L. and Kress, V., 2008, Laboratory calibration of chemical volcanic gas sampling techniques using an artificial fumarole. Volcanology and Geothermal Research, 174, 295-306.
  13. Ohba, T., Hirabayashi, J., and Yoshida, M., 1994, Equilibrium temperature and redox state of volcanic gas at Unzen volcano, Japan. Volcanology and Geothermal Research, 60, 263-272.
  14. Ohba, T., Hirabayashi, J., Nogami, K., Kusakabe, M., and Yoshida, M., 2008, Magma degassing process during the eruption of Mt. Unzen, Japan in 1991 to 1995: Modeling with the chemical composition of volcanic gas. Volcanology and Geothermal Research, 175, 120-132.
  15. Oskarsson, N., 1984, Monitoring of fumarole discharge during the 1975-1982 rifting in Krafla volcanic center, north Iceland. Volcanology and Geothermal Research, 22, 97-121.
  16. Qinhan, J., Wenjun, Y., Aimin, Y., Xiaodan, T., and Fendi, W., 1997, Helium direct current discharge ionization detector for gas chromatography. Chromatography A, 761, 169-179.
  17. Saito, M.A. and Moffett, J.W., 2002, Temporal and spatial variability of cobalt in the Atlantic Ocean. Geochimica et Cosmochimica Acta, 66, 1943-1953.
  18. Shinohara, H., 2005, A new technique to estimate volcanic gas composition: Plume measurements with a portable multi-sensor system. Volcanology and Geothermal Research, 143, 319-333.
  19. Shinohara, H., Ohba, T., Kazahaya K., and Takahashi, H., 2008, Origin of volcanic gases discharging from a cooling lava dome of Unzen volcano, Japan. Volcanology and Geothermal Research, 175, 133-140.
  20. Siovaldason, G.E. and Elisson, G,, 1968, Collection and analysis of volcanic gases at Surtsey, Iceland. Geochimica et Cosmochimica Acta, 32, 797-805.
  21. Smith, J.G., Dehn, J., Hoblitt, R.P., LaHusen, R.G., Lowenstern, J.B., Moran, S.C., McClelland L., McGee, K.A., Nathenson, M., Okubo, P.G., Pallister, J.S., Poland, M.P., Power, J.A., Schneider, D.J., and Sisson, T.W., 2009, Volcano monitoring, in young, R., and Norby, L. (eds.) Geological monitoring: Boulder, Colorado. Geological Society of America, USA, 273-305.
  22. Sortino, F., Nonell, A., Toutain, J.P., Munoz, M., Valladon, M., and Volpicelli, G., 2006, A new method for sampling fumarolic gases: Analysis of major, minor, and metallic trace elements with ammonia solutions. Volcanology and Geothermal Research, 158, 244-256.
  23. Sparks, R.S.J., 2003, Forecasting volcanic eruptions. Earth and Planetary Science Letters, 210, 1-15.
  24. Xu, J., Liu, G., Wu, J., Ming, Y., Wang, Q., Cui, D., Shangguan, Z., Pan, B., Lin, X., and Liu, J., 2012, Recent unrest of Changbaishan Volcano, northeast China: A precursor of a future eruption. Geophysical Research Letters, 39, 1-7.
  25. Yun, S.H., Won, C.K., and Lee, M.W., 1993, Cenozoic volcanic activity and petrochemistry of volcanic rocks in the Mt. Paektu area. The Geological Society of Korea, 29, 291-307. (in Korean)
  26. Yun, S.H., Taniguchi, H., Wei, H., and Liu, J., 2007, Crisis of Baegdusan. The Korean Society of Economic and Environmental Geology Spring Conference, 130-132. (in Korean)
  27. Yun, S.H., 2010, Natural disaster: The sign of volcanic eruptions at the Baegdusan volcano. Korean Earth Science Society 2010 fall meeting, 3-7. (in Korean)
  28. Yun, S.H. and Lee, J.H., 2012, Analysis of unrest sign of activity at the Baegdusan Volcano. The Petrological Society of Korea, 21, 1-12. (in Korean)
  29. Yun, S.H., 2013, Volcanological interpretation of historical eruptions of Mt. Baekdusan volcano. Korean Earth Science Society, 34, 456-469. (in Korean)