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BiFeO3-based Lead-free Piezoelectric Ceramics

비스무스 페라이트계 무연 압전 세라믹스

  • Choi, Jin-Hong (Department of Semiconductor & Display Engineering, Hoseo University) ;
  • Kim, Hyun-Ah (Department of Materials Science & Engineering, Hoseo University) ;
  • Han, Seung-Ho (Electronic Materials and Device Research Center, Korea Electronics Technology Institute) ;
  • Kang, Hyung-Won (Electronic Materials and Device Research Center, Korea Electronics Technology Institute) ;
  • Lee, Hyeung-Gyu (Electronic Materials and Device Research Center, Korea Electronics Technology Institute) ;
  • Kim, Jeong-Seog (Department of Semiconductor & Display Engineering, Hoseo University) ;
  • Cheon, Chae-Il (Department of Semiconductor & Display Engineering, Hoseo University)
  • 최진홍 (호서대학교 반도체 디스플레이공학과) ;
  • 김현아 (호서대학교 신소재공학과) ;
  • 한승호 (전자부품연구원 전자소재응용연구센터) ;
  • 강형원 (전자부품연구원 전자소재응용연구센터) ;
  • 이형규 (전자부품연구원 전자소재응용연구센터) ;
  • 김정석 (호서대학교 반도체 디스플레이공학과) ;
  • 천채일 (호서대학교 반도체 디스플레이공학과)
  • Received : 2012.07.05
  • Accepted : 2012.07.26
  • Published : 2012.09.01

Abstract

Recently, many lead-free piezoelectric materials have been investigated for the replacement of existing Pb-based piezoelectric ceramics because of globally increasing environmental interest. There has been remarkable improvement in piezoelectric properties of some lead-free ceramics such as $(Bi,Na)TiO_3-(Bi,K)TiO_3-BaTiO_3$, $(Na,K)NbO_3-LiSbO_3$, and so on. However, no one still has comparable piezoelectric properties to lead-based materials. Therefore, new lead-free piezoelectric ceramics are required. $BiFeO_3$ has a rhombohedrally distorted perovskite structure at room temperature and a very high Curie temperature ($T_C$= 1,100 K). And a very large electric polarization of 50 ~ 60 ${\mu}C/cm^2$ has been reported both in epitaxial thin film and single crystal $BiFeO_3$. Therefore, a high piezoelectric effect is expected also in a $BiFeO_3$ ceramics. The recent research activities on $BiFeO_3$ or $BiFeO_3$-based solid solutions are reviewed in this article.

Acknowledgement

Supported by : 지식경제부

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