Phenol Treatment Plasma Reactor of Dielectric Barrier Discharge

유전체 장벽 방전 플라즈마 반응기를 이용한 페놀 처리

  • Received : 2012.01.06
  • Accepted : 2012.03.21
  • Published : 2012.04.30


A Dielectric barrier discharge (DBD) plasma is shown in the present investigation to be effective of phenol degradation in the aqueous solutions in batch reactor with continuous air bubbling. Removal of phenol and effects of various parameters on the removal efficiency in the aqueous solution with high-voltage streamer discharge plasma are studied. The effect of 1st voltage (80 ~ 220 V), air flow rate (3 ~ 7 L/min), pH (3 ~ 11), electric conductivity of solution (4.16 ${\mu}S$/cm, deionized water) ~ 16.57 mS/cm (addition of NaCl 10 g/L) and initial phenol concentration (2.5 ~ 20.0 mg/L) were investigated. The observed results showed that phenol degradation was higher in the basic solution than that of the acidic. The optimum values on the 1st voltage and air flow rate for phenol degradation were 140 V and 6 L/min, respectively. It was considered that absorbance variation of $UV_{254}$ of phenol solution can be use as an indirect indicator of change of the non-biodegradable organic compounds within the treated phenol solution. Electric conductivity was not influenced the phenol degradation. To obtain the removal efficiency of phenol and COD of phenol over 97 % (initial phenol concentration, 10.0 mg/L), 80 min and 120 min were need, respectively. Phenol and COD degradation showed a pseudo-first order kinetics.


Supported by : 대구대학교


  1. 김동석, 박영식, 2007, 불용성 전극을 이용한 Rhodamine B의 전기화학적 탈색, 한국물환경학회지, 23(3), 377-384.
  2. 김동석, 박영식, 2009a, 전기-펜톤 공정에 의한 페놀의 전기화학적 분해, 한국환경보건학회지, 35(3), 201-208.
  3. 김동석, 박영식, 2009b, 전기분해와 UV 조사에 의한 수중 Rhodamine B의 제거(2), 한국환경과학회지, 18(6), 667-674.
  4. 김동석, 박영식, 2011a, 수처리용 유전체장벽 플라즈마 반응기에 대한 기초 연구, 한국환경과학회지, 20(5), 623-630.
  5. 김동석, 박영식, 2011b, 수중 플라즈마 공정을 이용한 Rhodamine B 염료의 제거, 한국환경보건학회지 37(3), 218-225.
  6. 김성근, 손현석, 임종권, 김지형, 조경덕, 2010, 초음파와 UV에 의한 페놀 분해 특성에 관한 연구, 대한환경공학회지, 32(7), 649-655.
  7. 박영식, 2004, UV/$TiO_{2}$와 유동층 반응기를 이용한 안료의 광촉매 탈색, 박영식, 한국환경과학회지, 13(10), 921-928.
  8. 박영식, 나영수, 안갑환, 2002, UV/$TiO_{2}$ 시스템을 이용한 Rhodamine B의 색도 제거, 환경위생학회지, 28(5), 59-64.
  9. 신인수, 최종봉, 이승목, 2004, UV/$TiO_{2}$광촉매 반응에 의한 페놀의 분해 특성, 한국물환경학회지, 20(5), 488-493.
  10. 윤석현, 2008, 하이브리드 수중플라즈마 토치의 방전특성 연구, 석사학위논문, 경남대학교.
  11. 이은주, 2005, 이온화가스에 의한 축산폐수 중 난분해성 물질 분해 특성, 박사학위논문, 전북대학교.
  12. 정재우, 박정욱, 박춘식, 2010, 오존 접촉 반응기의 용존 오존 농도 및 페놀 분해에 미치는 운전변수의 영향, 대한환경공학회지, 32(3), 241-247.
  13. 조진오, 2008, 저온 플라즈마를 이용한 폐수 중의 유기물 분해에 관한 연구, 석사학위논문, 제주대학교.
  14. 조훈제, 이선미, 김정규, 정진호, 2004, 감마선 처리에 의한 페놀과 2,4,6-트리클로로페놀의 분해제거 비교 연구, 대한환경공학회지, 26(9), 965-969.
  15. 최석순, 염승호, 차형준, 1997, Fenton 처리에 의한 페놀의 분해 특성, 대한위생학회지, 2(2), 29-35.
  16. APH-AWWA-WPCE, 1995, Standard methods for the examination of water and wastewater. 19th Ed., APHA, Washington D.C.
  17. Chen, Y. S., Zhang, X. S., Dai, Y. C., Yuan, W. K., 2004, Pulse high-voltage discharge plasma for degradation of phenol in aqueous solution, Sep. and Puri. Tech., 34, 5-12.
  18. Ha, D. Y., Cho, S. H., 2003, Comparison of UV/$H_{2}O_{2}$ and $TiO_{2}$ photocatalytic oxidation in the dyeing wastewater treatment efficiency, J. of KSEE., 25(9), 1123-1131.
  19. Hao, X., Zhou, M., Xin, Q., Lei, L., 2007, Pulsed discharge plasma induced Fenton-like reactions for the enhancement of the degradation of 4-chlorophenol in water, Chemosphere, 66, 2185-2192.
  20. Joo, D. J., Kim, J. Y., Shin, W. S., Lee, S. H., Kim, Y. H., Lee, J. D., Choi, S. J., 2002, Effect of protozonation in drinking water treatment using polyamine flocculant, Environ. Eng. Sci., 7(4), 191-198.
  21. Jung, J. K., 2009, Generation apparatus and method on the water plasma torch with high-density, Korean Patent, 10-0924649.
  22. Kim, D. S., Park, Y. S., 2007, Decolorization of Rhodamine B by Fenton, Fenton-like, and photo- Fenton-like oxidation, J of Environ. Heal. Sci., 33(2), 150-157.
  23. Kim, H. S., Hong, S. J., 2004, Surface treatment technology using low temperature/atmosphere pressure plasma, News & Information for Chemical Engineers, 17(4), 21-27.
  24. Li, J., Sato., M., Ohshima, T., 2007, Degradation of phenol in water using a gas-liquid phase pulsed discharge plasma reactor, Thin solid Films, 515, 4283-4288.
  25. Matos, J., Laine, J., Herrmann, J.-M., 1998, Synergy effect in the photocatalytic degradation of phenol on a suspended mixture of titania and activated carbon, Appl. Catal. B: Environ., 18, 281-291.
  26. Merouani, D. R., Abdelmalek, F., Taleb, F., Martel, M., Semmound, A., 2011, Plasma treatment by gliding arc discharge of dyes/dye mixtures in the presence of inorganic salts, Arabian J. of Chem., In press.
  27. Sanada, A., Katzer, J. R., 1974, Catalytic oxidation of phenol in aqueous solution, Ind. Eng. Chem. Funda., 13, 127-134.
  28. Shi, J., Bian, W., Yin, X., 2009, Organic contaminants removal by the technique of pulsed high-voltage discharge in water, J of Hazard. Mater., 171, 924-931.
  29. Uhm, H. S., 2006, Atmospheric plasma and its applications, Journal of the Korean Vacuum Society, 15(2), 117-138.
  30. Zhang, R., Wang, L., Wu, Y., Guan, Z., 2006, Bacterial decontamination of water by bipolar pulsed discharge in a gas-liquid-solid three-phase discharge reactor, IEEE Trans. on Plasma Sci., 34(4), 1370-1374.
  31. Zhang, R., Zhang, C., Cheng, X. X., Wang, L., Wu, Y., Guan, Z., 2007, Kinetics of decolorization of azo dye by bipolar pulsed barrier discharge in a three- phase discharge plasma, J of Hazard. Mater., 142, 105-110.
  32. Zilli, M., Converi, A., Lodi, A., Del Borghi, M., Ferriolo, G., 1993, Phenol removal from waste gases with a biological filter by Pseudomonas putita, Biotechnol. Bioneg., 41(1), 693-699.

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