Applied Chemistry for Engineering (공업화학)
- Volume 21 Issue 6
- /
- Pages.670-675
- /
- 2010
- /
- 1225-0112(pISSN)
- /
- 2288-4505(eISSN)
Synthesis of Vinyl-nano Silica Ball Composite : Its Application to Clearcoat
비닐-나노실리카볼 화합물의 클리어코트 특성 연구
- Kim, Bong-Gyeom (Department of Chemical Engineering, Hoseo University) ;
- Park, Gun-Hee (Department of Chemical Engineering, Hoseo University) ;
- Lee, Yong-Hwa (Department of Chemical Engineering, Hoseo University) ;
- Noh, Seung-Man (PPG Korea) ;
- Lee, Jae-Woo (PPG Korea) ;
- Park, Seung-Kyu (Department of Chemical Engineering, Hoseo University)
- Received : 2010.10.20
- Accepted : 2010.11.19
- Published : 2010.12.10
Abstract
Inorganic-organic hybrid material such as vinyl-nano sized silica ball was synthesized by acrylo-alkoxysilane and nano silica ball with different particle size. And then they were formulated into acrylic-melamine clearcoat. This material is fully characterized with various analytical methods and applied for strength measurement. The glossy effect, matting effect and anti-scratching properties of materials were investigated for further growth and maintenance. When the particle size of nano silica ball is 20~30 nm, the glossy retain effect was increased by 7% compared to bare acrylic-melamine clearcoat. When a commercially available silica Aerosil 200 (Hydrophilic fumed silica, average particle size 12 nm, Degussa) react with vinyl alkoxysilane vinyl-fumed silica complex form. The vinyl-fumed silica along with clearcoat increases only 2% increase at glossy retain. Nano-scratch test results also support the glossy retain effect of vinyl nano-sized silica ball in clearcoat.
File
Acknowledgement
Grant : 지역연계기술개발사업
References
- High-performance organic coatings, Edited by Anand S. Khanna, CRC Press (ISBN 978-1-4200-7969-2), USA; Woodhead Publishing Limited (ISBN 978-1-84569-265-0), Cambridge England Rozenberg, B. A.; Tenne, R. p 407-428 (2008).
- W. M. Weigert, A. Kleemann, and G. Schreyer, Chem. Ztg., 99, 19 (1975).
- A. Jurgetz, Automotive paint performance, Met. Finish., 93, 53 (1995).
- M. Lonyuk, M. Bosma, C. A. M. Vijverberg, and M. Janssen, Prog. Org. Coat., 61, 308 (2008). https://doi.org/10.1016/j.porgcoat.2007.09.036
- B. A. Rozenberg and R. Tenne, Prog. Polym. Sci., 33, 40 (2008). https://doi.org/10.1016/j.progpolymsci.2007.07.004
- J. Chen and M. D. Soucek, Eur. Polym. J., 39, 505 (2003). https://doi.org/10.1016/S0014-3057(02)00239-2
- A. Valet, Prog. Org. Coat., 35, 223 (1999). https://doi.org/10.1016/S0300-9440(99)00018-1
- D. A. Ley, D. E. Fiori, and R. J. Quinn, Prog. Org. Coat., 35, 109 (1999). https://doi.org/10.1016/S0300-9440(99)00010-7
- K. J. Van den Berg, L. G. J. Van den Hen, and H. J. W. Van den Haak, Prog. Org. Coat., 110, 61 (2008).
- J. L. Richardson, Met. Finish., 98, 34 (2000).
- K. Adamsons, G. Blackman, B. Gregorovich, L. Lin, and R. Matheson, Prog. Org. Coat., 34, 64 (1997). https://doi.org/10.1016/S0300-9440(98)00022-8
- P. Kardar, M. Ebrahimi, and S. Bastani, Prog. Org. Coat., 62, 321 (2008). https://doi.org/10.1016/j.porgcoat.2008.01.015
- Additives for polymers, August 24, 2 (2004).
- F. Aloui, A. Ahajji, Y. Irmouli, B. George, B. Charrier, and A. Merlin, Appl. Surf. Sci., 253, 3737 (2007). https://doi.org/10.1016/j.apsusc.2006.08.029
- U. S. Patent 6228799 B1 (2001).
- D. Fauchadour, T. Jeanson, J-N. Bousseau, and B. Echalier/Rhodia Rare Earths and Silica Systems, Lyon, France, Paint & Coatings Industry, August 1 (2005).
- S. Zhou, L. Wu, J. Sun, and W. Shen, Prog. Org. Coat., 45, 33 (2002). https://doi.org/10.1016/S0300-9440(02)00085-1
- K. Adamsons, Progress in Polymer Science, 25, November, 1363 (2000).
- F. Bauer, R. Flyunt, K. Czihal, H. Langguth, R. Mehnert, R. Schubert, and M. R. Buchmeiser, Prog. Org. Coat., 60, 121 (2007). https://doi.org/10.1016/j.porgcoat.2007.07.005
- J. D. Cho, Y. B. Kim, H. T. Ju, and J. H. Hong, Macromol. Res., 13, 362 (2005). https://doi.org/10.1007/BF03218467
- Z. Ranjbar and S. Rastegar, Prog. Org. Coat., 65, 125 (2009). https://doi.org/10.1016/j.porgcoat.2008.10.006
- S. K. Park, J. Y. Kim, and W. G. Cho, J. Soc. Cosmet. Scientists Korea, 20, 321 (2004).
- S. B. Yoon, J. Y. Kim, J. H. Kim, Y. J. Park, S. K. Park, and J. S. Yu, J. Mater. Chem., 17, 1758 (2007). https://doi.org/10.1039/b617471j
- S. Hofacker, M. Mechtel, M. Mager, and H. Kraus, Prog. Org. Coat., 45, 159 (2002). https://doi.org/10.1016/S0300-9440(02)00045-0
- M. Kciuk, S. Kcuik, and R. Turczyn, Journal of Achievements in Materials and Manufacturing Engineering, 33, 135 (2009).
- L. Lin, G. S. Blackman, and R. R. Matheson, Mater. Sci. Eng., A317, 163 (2001).
- H. Zhang, L. Tang, Z. Zhang, L. Gu, Y. Xu, and C. Eger, Tribol. Int., 43, 83 (2010). https://doi.org/10.1016/j.triboint.2009.05.022