DOI QR코드

DOI QR Code

A Lattice Model for Intra-molecular and Inter-molecular Association in Mixture containing Surfactants

계면활성제를 함유한 혼합물에서 내외부 분자회합을 위한 격자모델

  • Shin, Moon-Sam (Department of Cosmetic Science, Chungwoon University)
  • 신문삼 (청운대학교 화장품과학과)
  • Received : 2009.12.18
  • Accepted : 2010.05.13
  • Published : 2010.05.31

Abstract

Intra-molecular association is an important contribution to the overall hydrogen bonding in surfactant systems, especially in systems of colloidal and biological interest. Amphiphile systems, especially micelle and microemulsion systems, showed highly non-ideal behavior due to the intermolecular association and intra-molecular association. The objective of this research is to present a lattice fluid equation of state that combines the quasi-chemical nonrandom lattice fluid model with modified Veytsman statistics for intra + inter molecular association to calculate phase behavior for mixture containing surfactant systems. The lattice model could describe the literature data well for alkane and surfactant systems.

References

  1. M. I. Davis, Thermochim. Acta 190, pp. 259-265, 1991. https://doi.org/10.1016/0040-6031(91)85252-D
  2. H. H. Lai, L. J. Chen, J. Chem. Eng. Data, 44, pp. 251-253, 1996
  3. F. J. Carmona, V. R. Bhethanabotla, S. C. Campbell, J. A. Gonzalez, I. Garcia de la Fuente, J. C. Cobos, J. Chem. Thermodyn., 33, pp. 47-59, 2001 https://doi.org/10.1006/jcht.2000.0709
  4. F. J. Carmona, J. A. Gonzalez, I. Garcia de la Fuente, J. C. Cobos, V. R. Bhethanabotla, S. C. Campbell, J. Chem. Eng. Data, 45, pp. 699-703, 2000 https://doi.org/10.1021/je990292n
  5. B. A. Veytsman, J. Phys. Chem, 94, p. 8499, 1990 https://doi.org/10.1021/j100386a002
  6. D. Missopolinou, K. Ioannou, I. Prinos, C. Panayiotou, Z. Phys. Chem., 216, pp. 905-918, 2002. https://doi.org/10.1524/zpch.2002.216.7.905
  7. D. Missopolinou, I. Tsivintzelis, C, Panayiotou C, Fluid Phase Equilib, 238, pp. 204-209, 2005. https://doi.org/10.1016/j.fluid.2005.10.005
  8. J. H. Lee, C. S. Lee, Ind. Eng. Chem. Res., 45, pp. 1817-1821, 2006. https://doi.org/10.1021/ie051180u
  9. M. S. Shin, K. Yoo, C. S. Lee, H. Kim, Korean J. Chem. Eng., 23, pp. 469-475, 2006. https://doi.org/10.1007/BF02706751
  10. M. S. Shin, K. Yoo, C. S. Lee, H. Kim, Korean J. Chem. Eng., 23, pp. 476-481, 2006. https://doi.org/10.1007/BF02706752
  11. S. Jang, M. S. Shin, H. Kim, Korean J. Chem. Eng., 26, pp. 225-229, 2009. https://doi.org/10.1007/s11814-009-0037-6
  12. M. S. Shin, H. Kim, Fluid Phase Equilib., 246, pp. 79-88, 2006. https://doi.org/10.1016/j.fluid.2006.05.019
  13. R. L. Brinkey, R. B. Gupta, Ind. Eng. Chem. Res.,37, pp. 4823-4827, 1998. https://doi.org/10.1021/ie970740p
  14. C S. Lee, K. P. Yoo, B. H. Park, J. W. Kang, Fluid Phase Equilib., 187-188, pp. 433-441, 2001. https://doi.org/10.1016/S0378-3812(01)00555-6
  15. M. S. Shin, H. Kim, Fluid Phase Equilib., 256, pp. 27-33, 2007. https://doi.org/10.1016/j.fluid.2006.12.002
  16. J. Kang, K. Yoo, H. Kim, J. Lee, D. Yang, C. Lee, Int. J. Thermophys., 22, 487, 2001. https://doi.org/10.1023/A:1010726915591
  17. H. Renon, J.M. Prausnitz, Chem. Eng. Sci., 22, pp. 299-307, 1967. https://doi.org/10.1016/0009-2509(67)80116-7
  18. C. G. Panayiotou, J. Phys. Chem., 92, pp. 2960-2970, 1988. https://doi.org/10.1021/j100321a048
  19. I. Nagata, K. Tamura, Thermochimica Acta, 57, pp. 331-349, 1982. https://doi.org/10.1016/0040-6031(82)80044-0
  20. H. V. Kehiaian, Fluid Phase Equilib., 13, pp. 243-252, 1983. https://doi.org/10.1016/0378-3812(83)80098-3
  21. H. V. Kehiaian, Pure Appl. Chem., 57, 15, 1985. https://doi.org/10.1351/pac198557010015
  22. J. A. Gonzalez, J. C. Cobos, F. J. Carmona, I. Garcia de la Fuente, V. R. Bhethanabolta, S. W. Campbell, Phys.Chem. Chem. Phys., 3, pp. 2856-2865, 2001. https://doi.org/10.1039/b100765n
  23. S. G. Oh, J. G. Kim, J. D. Kim, Korean J. Chem. Eng., 4, pp. 53-57, 1987. https://doi.org/10.1007/BF02698099
  24. M. S. Shin, H. Kim, J. Chem. Thermodyn., 40, pp. 1110-1115, 2008. https://doi.org/10.1016/j.jct.2008.02.016
  25. J. H. Lee, C. S. Lee, Ind. Eng. Chem. Res., 45, pp. 1817-1821, 2006. https://doi.org/10.1021/ie051180u