- Volume 26 Issue 5
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Enhancement of Ozone and Carbon Monoxide Associated with Upper Cut-off Low during Springtime in East Asia
- Moon, Yun-Seob (Department of Environmental Education, Korea National University of Education) ;
- Drummond, James R. (Department of Physics, University of Toronto)
- Received : 2009.09.21
- Accepted : 2010.09.03
- Published : 2010.10.31
In order to verify the enhancement of ozone and carbon monoxide (CO) during springtime in East Asia, we investigated weather conditions and data from remote sensors, air quality models, and air quality monitors. These include the geopotential height archived from the final (FNL) meteorological field, the potential vorticity and the wind velocity simulated by the Meteorological Mesoscale Model 5 (MM5), the back trajectory estimated by the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model, the total column amount of ozone and the aerosol index retrieved from the Total Ozone Mapping Spectrometer (TOMS), the total column density of CO retrieved from the Measurement of Pollution in the Troposphere (MOPITT), and the concentration of ozone and CO simulated by the Model for Ozone and Related Chemical Tracers (MOZART). In particular, the total column density of CO, which mightoriginate from the combustion of fossil fuels and the burning of biomass in China, increased in East Asia during spring 2000. In addition, the enhancement of total column amounts of ozone and CO appeared to be associated with both the upper cut-off low near 500 hPa and the frontogenesis of a surface cyclone during a weak Asian dust event. At the same time, high concentrations of ozone and CO on the Earth's surface were shown at the Seoul air quality monitoring site, located at the surface frontogenesis in Korea. It was clear that the ozone was invaded by the downward stretched vortex anomalies, which included the ozone-rich airflow, during movement and development of the cut-off low, and then there was the catalytic photochemical reaction of ozone precursors on the Earth's surface during the day. In addition, air pollutants such as CO and aerosol were tracked along both the cyclone vortex and the strong westerly as shown at the back trajectory in Seoul and Busan, respectively. Consequently, the maxima of ozone and CO between the two areas showed up differently because of the time lag between those gases, including their catalytic photochemical reactions together with the invasion from the upper troposphere, as well as the path of their transport from China during the weak Asian dust event.
Total column density of CO;Total column amounts of ozone;Upper cut-off low;Vortex anomalies;Catalytic chemical reaction
Supported by : Korea Research Foundation
- Austin, J.F. and R.P. Midgley (1994) The climatology of the jet stream and stratospheric intrusions of ozone over Japan, Atmospheric Environment, 28A, 39-52. https://doi.org/10.1016/1352-2310(94)90021-3
Cardenas, K.C., J.F. Austin, R.A. Burgess, K.C. Clemitshaw,
S. Dorling, S.A. Penkett, and R.M. Harrison
(1998) Correlations between CO,
$NO_y,\;O_3$and non-methane hydrocarbons and their relationships with meteorology during winter 1993 on the north Norfolk coast, U.K., Atmospheric Environment, 32A, 3339-3351. https://doi.org/10.1016/S1352-2310(97)00445-7
- Cicerone, R.J. (1988) How has the atmospheric concentration of CO changed? The Changing Atmosphere, J. Wiley & Sons Ltd., New York, 49-66.
- Cooper, O.R., J.L. Moody, J.C. Davenport, S.J. Oltmans, B.J. Johnson, X. Chen, P.B. Shepson, and J.T. Merrill (1998) Influence of springtime weather systems on vertical ozone distributions over three North American sites, Journal of Geophysical Research, 103, 22001-22013. https://doi.org/10.1029/98JD01801
- Davies, T.D. and E. Schuepbach (1994) Episode of high ozone concentration at the surface resulting from transport down from the upper troposphere/lower stratosphere: A review and case studies, Atmospheric Environment, 28, 53-68. https://doi.org/10.1016/1352-2310(94)90022-1
- De laat, A.T., J. Lelieveld, G.J. Roelofs, R.R. Dickerson, and J.M. Lobert (2001) Source analysis of carbon monoxide pollution during INDOX 1999, Journal of Geophysical Research, 106, 28481-28495. https://doi.org/10.1029/2000JD900769
- Drummond, J.R. and G.S. Mand (1996) The Measurements of Pollution in the Troposphere (MOPITT) instrument: Overall performance and calibration requirements, Journal of Atmospheric Oceanic Technology, 13, 314-320. https://doi.org/10.1175/1520-0426(1996)013<0314:TMOPIT>2.0.CO;2
- Drummond, J.R., L. Yurganov, P. Novelli, N. Pougatchev, and F. Murcray (2002) Validation of MOPITT retrievals of carbon monoxide, 24th IGASSS (International Geoscience & Remote Sencing Symposium) 2002, Toronto, Canada, 0-7803-7537-8/02/.
- Eagleman, J.R. (1985) Meteororlogy, the atmosphere in action, Wadsworth Publishing Company, 156-171.
- Fang, J., A. Chen, C. Peng, S. Zhao, and L. Ci (2001) Changes in forest biomass carbon storage in china between 1949 and 1998, Science, 292, 2320-2321. https://doi.org/10.1126/science.1058629
- Fenn, M.A., E.V. Browell, C.F. Butter, W.B. Grant, S.A. Kooi, M.B. Clayton, G.L. Gregory, R.E. Newell, Y. Zhu, J.E. Dibb, H.E. Fuelberg, B.E. Anderson, A.R. Bandy, D.R. Blake, J.D. Bradshaw, B.G. Heikes, G.W. Sachse, S.T. Sandholm, H.B. Singh, R.W. Talbot, and D.C. Thornton (1999) Ozone and aerosol distribution and air mass characteristics over the South pacipic during the burning season, Journal of Geophysical Research, 104, 16197-16212. https://doi.org/10.1029/1999JD900065
- Fioletov, V.E., J.B. Kerr, E.W. Hare, G.J. Labow, and R.D. McPeters (1999) An assessment of the world ground-based total ozone network performance from the comparison with satellite data, Journal of Geophysical Research, 104, 1737-1748. https://doi.org/10.1029/1998JD100046
- Hobbs, P.V. (2000) Introduction to Atmospheric Chemistry, Cambridge University Press, Cambridge, UK, 143-163.
- Horowitz, L.W., S. Walters, D.L. Mauzerall, L.K. Emmons, P.J. Rasch, C. Granier, X. Tie, J.F. Lamarque, M.G. Schultz, G.S. Tyndall, J.J. Orlando, and G.P. Brasseur (2003). A global simulation of tropospheric ozone and related tracers: Description and evaluation of MOZART, version 2 (PDF), Journal of Geophysical Research, 108 (D24), 4784. https://doi.org/10.1029/2002JD002853
Hubler, G., D.D. Montzka, R.B. Norton, P.C. Murphy, F.C.
Fehsenfeld, S.C. Liu, B.A. Ridley, J.G. Walega,
E. Atlas, F.E. Grahek, L.E. Heidt, J. Merrill, B.J.
Huebert, and B.A. Bodhaine (1992) Total reactive
$(NO_y)$in the remote Pacific troposphere and its correlation with $O_3$and CO: Mauna Loa observatory photochemistry experiment 1988, Journal of Geophysical Research, 97, 10427-10447. https://doi.org/10.1029/91JD03112
- Jacob, D.J. (1999) Introduction to Atmospheric Chemistry, Princeton University Press, Chichester, West Sussex, 143-163.
- Khalil, M.A. and R.A. Rasmussen (1994) Global decrease in atmospheric carbon monoxide concentration, Nature, 370, 639-641. https://doi.org/10.1038/370639a0
- Kim, Y.K., H.W. Lee, J.K. Park, and Y.S. Moon (2002) The stratosphere-troposphere exchange of ozone and aerosols over Korea, Atmospheric Environment, 36A, 449-463. https://doi.org/10.1016/S1352-2310(01)00370-3
- Kondratyev, K.Y. and C. Varotsos (2000) Atmospheric ozone variability: Implications for climate change, human health and ecosystems, Springer-Verlag Berlin Heidelberg, New York, 617pp.
Marenco, A., M. Macaigne, and S. Prieur (1989) Meridional,
and vertical CO and
$CH_4$distributions in the background troposphere (70 N-60 S; 0-12 km altitude) from scientific aircraft measurements during the STRATOZ III experiment (June 1984), Atmospheric Environment, 23, 185-200. https://doi.org/10.1016/0004-6981(89)90111-X
- Moon, Y.S., Y.K. Kim, K. Strong, S.H. Kim, Y.K. Lim, I.B. Oh, and S.K. Song (2002) Surface ozone episode due to stratosphere-troposphere exchange and free troposphere-boundary layer exchange in Busan during Asian dust events, Korean Environmental Sciences Society, 11(5), 419-436. https://doi.org/10.5322/JES.2002.11.5.419
- Novelli, P.C., K.A. Masarie, P.P. Tans, and P.M. Lang (1994) Recent changes in atmospheric carbon monoxide, Science, 263, 1587-1590 https://doi.org/10.1126/science.263.5153.1587
Pan, L., D.P. Edwards, J.C. Gille, M. Smith, and J.R. Drummond
(1995) Satellite remote sensing of tropospheric
$CH_4:$Forward model studies of the MOPITT instrument, Apply Optics, 34, 6976-6988. https://doi.org/10.1364/AO.34.006976
- Pan, L., J.C. Gille, D.P. Edwards, and P.L. Bailey (1998) Retrieval of tropospheric carbon monoxide for the MOPITT, Journal of Geophysical Research, 103, 32277-32290. https://doi.org/10.1029/98JD01828
- Reichle, H.G., V.S. Connors, J.A. Holland, R.T. Sherrill, H.A. Wallio, J.C. Casas, E.P. Condon, B.B. Gormsen, and W. Seiler (1990) The distribution of middle tropospheric carbon monoxide during early October 1984, Journal of Geophysical Research, 95, 9845-9856. https://doi.org/10.1029/JD095iD07p09845
- Reichle, H.G. and Coauthors (1999) Space shuttle based global CO measurements during April and October 1994, MAPS instrument, data reduction, and data validation, Journal of Geophysical Research, 104, 21443-21454 https://doi.org/10.1029/97JD03299
- Rodrers, C.D. (1976) Retrieval of atmospheric temperature and composition from remote measurements of thermal radiation, Review of Geophysical Space Physics, 14, 609-624. https://doi.org/10.1029/RG014i004p00609
- Seinfeld, J.H. and S.N. Pandis (1998) Atmospheric Chemistry and Physics: From Air Pollution to Climate Change, John Wiley & Sons, Inc., New York/Chichester/Weinheim/Brisbane/Singapore/Tronto, p. 1326.
- Smith, W.L. (1968) An improved method for calculating tropospheric temperature and moisture from satellite radiometer measurements, Monthly Weather Review, 96, 387-396. https://doi.org/10.1175/1520-0493(1968)096<0387:AIMFCT>2.0.CO;2
- Thompson, A.M., K.E. Pickering, R.R. Dickerson, W.G. Ellis, and D.J. Jacob (1994) Convective transport over the central United States and its role in regional CO and ozone budgets, Journal of Geophysical Research, 99, 18703-18711. https://doi.org/10.1029/94JD01244
- Wang, J., J.C. Gille, P.L. Bailey, L. Pan, D. Edwards, and J.R. Drummond (1999) Retrieval of tropospheric carbon monoxide profiles from high-resolution interferometer observations: A new Digital Gas Correlation (DGC) method and applications, Journal of Atmospheric Sciences, 56, 219. https://doi.org/10.1175/1520-0469(1999)056<0219:ROTCMP>2.0.CO;2
- Warneck, P. (1988) Chemistry of the natural atmosphere, Academic Press, New York, 131-175.
- Warneck, P. (2000) Chemistry of the Natural Atmosphere, Academic Press, p. 923.
- Warner, J.X., J.C. Gille, D.P. Edwards, D.C. Ziskin, M.W. Smith, and P.L. Bailey (2001) Cloud detection and clearing for the EOS Terra satellite Measurement of Pollution in the Troposphere (MOPITT) experiment, Applied Optics, 40(8), 1269-1284. https://doi.org/10.1364/AO.40.001269
- Yurganov, L.N., E.I. Grechko, and A.V. Dzhola (1995) Carbon monoxide and total ozone in Arctic and Antarctic regions: Seasonal variations, long-term trands and relationships, Science Total Environment, 160/161, 831-840. https://doi.org/10.1016/0048-9697(95)04416-X
- Yurganov, L.N., E.I. Grechko, and A.V. Dzhola (1997) Variations of carbon monoxide density in the total atmospheric column over Russia between 1970 and 1995: Upward trend and disturbances, attributed to the influence of volcanic aerosols and forest fires, Geophysical Research Letter, 24, 1231-2134. https://doi.org/10.1029/97GL50990
- ) Using WRF-SMOKE-CMAQ (MADRID) During Springtime in the Korean Peninsula vol.32, pp.3, 2011, https://doi.org/10.5467/JKESS.2011.32.3.276